trans-γ-bis(2-(phenylazo)pyridine)ruthenium(II) chloride

Base Information

Chemical Name:trans-γ-bis(2-(phenylazo)pyridine)ruthenium(II) chloride
CAS No.:73952-48-4
Molecular Formula:C₂₂H₁₈Cl₂N₆Ru
Molecular Weight:538.401
Hs Code.:

Synonyms:trans-γ-bis(2-(phenylazo)pyridine)ruthenium(II) chloride

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Chemical Property of trans-γ-bis(2-(phenylazo)pyridine)ruthenium(II) chloride

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Technology Process of trans-γ-bis(2-(phenylazo)pyridine)ruthenium(II) chloride

There total 10 articles about trans-γ-bis(2-(phenylazo)pyridine)ruthenium(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 2569-57-5
2-(phenylazo)pyridine

: C₉₄H₈₇Cl₃N₁₁O₁₄Ru

: 73952-48-4,84027-71-4,73926-31-5,288614-83-5,131724-86-2,74006-30-7
Ru(2-(phenylazo)pyridine)2Cl₂

: C₁₀₅H₉₆ClN₁₄O₁₄Ru⁽¹⁺⁾*F₆P^(1-)

Guidance literature:: 2-(phenylazo)pyridine; C₉₄H₈₇Cl₃N₁₁O₁₄Ru; With triethylamine; lithium chloride; In ethanol; water; Reflux;

With ammonium hexafluorophosphate; In ethanol; water;
DOI:10.1021/jacs.7b05458

Reference yield: 70.0%

: 14898-67-0
ruthenium(III) chloride trihydrate

: [bis-[2-(phenylazo)pyridine]silver(I)] perchlorate

: 74006-30-7
cis-β-bis(2-(phenylazo)pyridine)ruthenium(II) chloride

: 73952-48-4
trans-γ-bis(2-(phenylazo)pyridine)ruthenium(II) chloride

: 84027-71-4
cis-trans-cis-dichlorobis(2-phenylazopyridine)ruthenium(II)

Guidance literature:: In methanol; byproducts: silver chloride; heating (water bath, 40°C, 15 min, Ru compd. /Ag compd. 1/1); filtration, washing (MeOH), drying (vac.), extn. (CH2Cl2, removal AgCl), crystn. (hexane), filtrates and washings concd., pptn. (H2O), drying, chromy. (silica gel, CH2Cl2/CH3CN);
DOI:10.1039/DT9910003249

Reference yield: 45.0%

: 2569-57-5
2-(phenylazo)pyridine

: [Ru(2,2'-bipyridine)Cl₃]n*xH₂O

: cis-dichloro(2,2′-bipyridine)ruthenium(II)chloride

: 74006-30-7
cis-β-bis(2-(phenylazo)pyridine)ruthenium(II) chloride

: 84027-71-4
cis-trans-cis-dichlorobis(2-phenylazopyridine)ruthenium(II)

: 73952-48-4,84027-71-4,73926-31-5,288614-83-5,131724-86-2,74006-30-7
Ru(2-(phenylazo)pyridine)2Cl₂

: α-[Ru(2-phenylazopyridine)(2,2'-bipyridine)Cl2]*H2O

Guidance literature:: In N,N-dimethyl-formamide; soln. (Ru(bpy)Cl3)n*xH2O in DMF was mixed withazpy and refluxed for 50 min; react. mixt. was filtered and evapd. to dryness, residue was dissolved in CHCl3, filtered and concd., chromy. on alumina with CHCl3 as eluent, recrystn. from CHCl3-ether; elem. anal.;
DOI:10.1021/ic035390f