Ru(2-(phenylazo)pyridine)2Cl₂

Base Information

• Chemical Name: Ru(2-(phenylazo)pyridine)2Cl₂
• CAS No.: 74006-30-7
• Molecular Formula: C₂₂H₁₈Cl₂N₆Ru
• Molecular Weight: 538.401
• Mol file: 74006-30-7.mol

Synonyms:

Chemical Property of Ru(2-(phenylazo)pyridine)2Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(2-(phenylazo)pyridine)2Cl₂

There total 14 articles about Ru(2-(phenylazo)pyridine)2Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

2-(phenylazo)pyridine (2569-57-5) + C94H87Cl3N11O14Ru → Ru(2-(phenylazo)pyridine)2Cl2 (73952-48-4,84027-71-4,73926-31-5,288614-83-5,131724-86-2,74006-30-7) + C105H96ClN14O14Ru(1+)*F6P(1-)

Guidance literature:

2-(phenylazo)pyridine; C₉₄H₈₇Cl₃N₁₁O₁₄Ru; With triethylamine; lithium chloride; In ethanol; water; Reflux;

With ammonium hexafluorophosphate; In ethanol; water;

DOI:10.1021/jacs.7b05458

Reference yield: 70.0%

ruthenium(III) chloride trihydrate (14898-67-0) + [bis-[2-(phenylazo)pyridine]silver(I)] perchlorate → cis-β-bis(2-(phenylazo)pyridine)ruthenium(II) chloride (74006-30-7) + trans-γ-bis(2-(phenylazo)pyridine)ruthenium(II) chloride (73952-48-4) + cis-trans-cis-dichlorobis(2-phenylazopyridine)ruthenium(II) (84027-71-4)

Guidance literature:

In methanol; byproducts: silver chloride; heating (water bath, 40°C, 15 min, Ru compd. /Ag compd. 1/1); filtration, washing (MeOH), drying (vac.), extn. (CH2Cl2, removal AgCl), crystn. (hexane), filtrates and washings concd., pptn. (H2O), drying, chromy. (silica gel, CH2Cl2/CH3CN);

DOI:10.1039/DT9910003249

Reference yield: 45.0%

2-(phenylazo)pyridine (2569-57-5) + [Ru(2,2'-bipyridine)Cl3]n*xH2O → cis-dichloro(2,2′-bipyridine)ruthenium(II)chloride + cis-β-bis(2-(phenylazo)pyridine)ruthenium(II) chloride (74006-30-7) + cis-trans-cis-dichlorobis(2-phenylazopyridine)ruthenium(II) (84027-71-4) + Ru(2-(phenylazo)pyridine)2Cl2 (73952-48-4,84027-71-4,73926-31-5,288614-83-5,131724-86-2,74006-30-7) + α-[Ru(2-phenylazopyridine)(2,2'-bipyridine)Cl2]*H2O

Guidance literature:

In N,N-dimethyl-formamide; soln. (Ru(bpy)Cl3)n*xH2O in DMF was mixed withazpy and refluxed for 50 min; react. mixt. was filtered and evapd. to dryness, residue was dissolved in CHCl3, filtered and concd., chromy. on alumina with CHCl3 as eluent, recrystn. from CHCl3-ether; elem. anal.;

DOI:10.1021/ic035390f

upstream raw materials:

benzoyl chloride

ruthenium(III) chloride trihydrate

trans-γ-bis(2-(phenylazo)pyridine)ruthenium(II) chloride

2-(phenylazo)pyridine

Downstream raw materials:

cis-trans-cis-dichlorobis(2-phenylazopyridine)ruthenium(II)

Ru(C₆H₅N₂C₅H₄N)2(NO₂)2

ruthenium(II)[2-(phenylazo)pyridine]2(CN)2