1-phenylvinyl-2,2-d2 dimethylcarbamate

Base Information

Chemical Name:1-phenylvinyl-2,2-d2 dimethylcarbamate
CAS No.:1573114-66-5
Molecular Formula:C₁₁H₁₃NO₂
Molecular Weight:193.214
Hs Code.:

Synonyms:1-phenylvinyl-2,2-d2 dimethylcarbamate

Suppliers and Price of 1-phenylvinyl-2,2-d2 dimethylcarbamate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-phenylvinyl-2,2-d2 dimethylcarbamate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-phenylvinyl-2,2-d2 dimethylcarbamate

There total 4 articles about 1-phenylvinyl-2,2-d2 dimethylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 17537-31-4
Acetophenone-methyl-d3

: 79-44-7
N,N-Dimethylcarbamoyl chloride

: 1573114-66-5
1-phenylvinyl-2,2-d2 dimethylcarbamate

Guidance literature:: Acetophenone-methyl-d3; With sodium hydride; In dimethylsulfoxide-d6; mineral oil; at 20 ℃; for 0.5h;

N,N-Dimethylcarbamoyl chloride; In dimethylsulfoxide-d6; mineral oil; at 20 ℃;

With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; d⁽⁴⁾-methanol; copper diacetate; at 60 ℃; for 16h; Schlenk technique; Inert atmosphere;
DOI:10.1021/ol500258q

Reference yield:

: 17537-31-4
Acetophenone-methyl-d3

: 79-44-7
N,N-Dimethylcarbamoyl chloride

: 1573114-66-5
1-phenylvinyl-2,2-d2 dimethylcarbamate

: C₁₁H₁₂⁽²⁾HNO₂

: C₁₁H₁₂⁽²⁾HNO₂

Guidance literature:: Acetophenone-methyl-d3; With sodium hydride; In dimethylsulfoxide-d6; mineral oil; at 20 ℃; for 0.666667h;

N,N-Dimethylcarbamoyl chloride; In dimethylsulfoxide-d6; mineral oil; at 20 ℃; Overall yield = 32 %; Overall yield = 0.485 g;
DOI:10.1002/ejoc.201600558

Reference yield:

: 98-86-2
acetophenone

: 1573114-66-5
1-phenylvinyl-2,2-d2 dimethylcarbamate

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / mineral oil; dimethyl sulfoxide / 0.5 h / 20 °C

1.2: 20 °C

2.1: d⁽⁴⁾-methanol; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver hexafluoroantimonate; copper diacetate / 16 h / 60 °C / Schlenk technique; Inert atmosphere

With silver hexafluoroantimonate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; d⁽⁴⁾-methanol; copper diacetate; sodium hydride; In dimethyl sulfoxide; mineral oil;
DOI:10.1021/ol500258q