trans-μ-dichlorobis[(2,6-diisopropyl-N-(4-methoxybenzyliden-2-ido)aniline)palladium(II)]

Base Information

• Chemical Name: trans-μ-dichlorobis[(2,6-diisopropyl-N-(4-methoxybenzyliden-2-ido)aniline)palladium(II)]
• CAS No.: 1334680-68-0
• Molecular Formula: C₄₀H₄₈Cl₂N₂O₂Pd₂
• Molecular Weight: 872.579
• Mol file: 1334680-68-0.mol

Synonyms:trans-μ-dichlorobis[(2,6-diisopropyl-N-(4-methoxybenzyliden-2-ido)aniline)palladium(II)]

Chemical Property of trans-μ-dichlorobis[(2,6-diisopropyl-N-(4-methoxybenzyliden-2-ido)aniline)palladium(II)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-μ-dichlorobis[(2,6-diisopropyl-N-(4-methoxybenzyliden-2-ido)aniline)palladium(II)]

There total 1 articles about trans-μ-dichlorobis[(2,6-diisopropyl-N-(4-methoxybenzyliden-2-ido)aniline)palladium(II)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

sodium tetrachloropalladate(II) + N-(4-methoxybenzylidene)-2,6-diisopropylbenzeneamine → trans-μ-dichlorobis[(2,6-diisopropyl-N-(4-methoxybenzyliden-2-ido)aniline)palladium(II)] (1334680-68-0)

Guidance literature:

With NaCH₃COO; In methanol; inert atmosphere using standard Schlenk techniques; soln. of Na2PdCl2, ligand and NaOAc (1:2:2 mol) stirred at room temp. for 6 h; product filtered off; washed (H2O, Et2O); dissolved in CH2Cl2; soln. filtered; filtrate evapd.; residue crystd. (CH2Cl2/hexane); elem. anal.;

DOI:10.1016/j.ica.2011.06.003

Reference yield: 83.0%

hexane (110-54-3) + trans-μ-dichlorobis[(2,6-diisopropyl-N-(4-methoxybenzyliden-2-ido)aniline)palladium(II)] (1334680-68-0) + trans-1,2-bis(4-pyridyl)ethylene (1135-32-6) → [Pr((4-MeO)C6H3CH=NC6H3-2,6-iPr2)Cl]2(μ-bpe)*0.5(hexane)

Guidance literature:

In dichloromethane; N2; Pd compd. and ligand (0.16:0.19 molar ratio), mixt. stirred for 22 hat room temp.; evapd., washed (ether), recrystd. (CH2Cl2/hexane), elem. anal.;

DOI:10.1016/j.jorganchem.2012.04.026

Reference yield: 80.0%

[2,2]bipyridinyl (366-18-7) + trans-μ-dichlorobis[(2,6-diisopropyl-N-(4-methoxybenzyliden-2-ido)aniline)palladium(II)] (1334680-68-0) + silver nitrate → [Pr((4-MeO)C6H3CH=NC6H3-2,6-iPr2)(ONO2)]2(μ-4,4'-bipyridine) (1384456-13-6)

Guidance literature:

In acetonitrile; N2; soln. of Pd compd. treated with AgNO3, mixt. stirred for 10 h at room temp., filtered, ligand added (1:2:1 molar ratio), stirred for 14 h; filtered, evapd., washed (ether), recrystd. (DCM/hexane), elem. anal.;

DOI:10.1016/j.jorganchem.2012.04.026

Downstream raw materials:

[Pr((4-MeO)C₆H₃CH=NC₆H₃-2,6-iPr₂)Cl]2(tpt)

[Pr((4-MeO)C6H3CH=NC6H3-2,6-iPr2)Cl]2(μ-bpt)

[Pr((4-MeO)C6H3CH=NC6H3-2,6-iPr2)(ONO2)]2(μ-4,4'-bipyridine)

[Pr((4-MeO)C6H3CH=NC6H3-2,6-iPr2)Cl]2(μ-4,4'-bipyridine)

Refernces