Technology Process of Manganese, dicarbonyl((1,2,3,4,5-eta5)-1-methyl-2,4-cyclopentadien-1-yl)(triphenylstibine)-
There total 3 articles about Manganese, dicarbonyl((1,2,3,4,5-eta5)-1-methyl-2,4-cyclopentadien-1-yl)(triphenylstibine)- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
tetrahydrofuran;
byproducts: NaBr, Ph2MeSiBr; Na((MeC5H4)(CO)2Mn(SiMePh2)) reacts quickly in THF with Ph3SbBr2 at room temp., after 5 min the solvent is removed and the (MeC5H5)(CO)2Mn(SbPh3) is extracted with petroleum ether; the soln. is concentrated and is cooled for 24 h to -30°C; washed with cold pentane; identification by elem. anal., IR, melting point, (1)H- and (13)C-NMR;
- Guidance literature:
-
In
acetonitrile;
Electrochem. Process; under N2 or Ar, electrocatalysis at 22°C at Pt-gauze electrode (200 μA), supporting electrolyte 0.1 N tetraethylammonium perchlorate;
DOI:10.1016/0022-328X(86)84060-8
- Guidance literature:
-
With
tetrahydrofuran;
In
tetrahydrofuran;
Irradiation (UV/VIS); the THF soln. of the complex compd. was deaerated and irradiated for 50 min at 0 °C, then the ligand was added and the soln. stirred for several h at room temp.; THF was removed in vac., the residue was dissolved, then filtered and crystd., elem. anal.;
DOI:10.1021/ja00339a012
