benzyldimethylsilylmethyl magnesium chloride

Base Information

• Chemical Name: benzyldimethylsilylmethyl magnesium chloride
• CAS No.: 49759-13-9
• Molecular Formula: C₁₀H₁₅ClMgSi
• Molecular Weight: 223.073
• Mol file: 49759-13-9.mol

Synonyms:benzyldimethylsilylmethyl magnesium chloride

Chemical Property of benzyldimethylsilylmethyl magnesium chloride

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of benzyldimethylsilylmethyl magnesium chloride

There total 1 articles about benzyldimethylsilylmethyl magnesium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzyl chloromethyl dimethyl silane (5356-99-0) → benzyldimethylsilylmethyl magnesium chloride (49759-13-9)

Guidance literature:

With magnesium; In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1021/jo302122f

Reference yield: 88.0%

benzyldimethylsilylmethyl magnesium chloride (49759-13-9) + 10-bromo-5,15-diphenylporphyrin → 10-(benzyldimethylsilyl)methyl-5,15-diphenylporphyrin

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; Diphenylphosphine oxide; In tetrahydrofuran; at 60 ℃; for 1h; Inert atmosphere;

DOI:10.1021/jo302122f

Reference yield: 80.0%

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + benzyldimethylsilylmethyl magnesium chloride (49759-13-9) → bis-[benzyl(dimethyl)silylmethyl](cycloocta-1,5-diene)platinum(II) (164856-07-9)

Guidance literature:

Ar; recrystallization (n-hexane); elem. anal.;

DOI:10.1016/0277-5387(94)00193-I

upstream raw materials:

benzyl chloromethyl dimethyl silane

Downstream raw materials:

4-[(Benzyl-dimethyl-silanyl)-methyl]-azetidin-2-one

β-(benzyldimethylsilyl)ethanol

tris[(benzyldimethylsilyl)methylene]tin chloride

bis-[benzyl(dimethyl)silylmethyl](cycloocta-1,5-diene)platinum(II)