282107-49-7

Upstream product

• 502761-67-3 (3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol 
• 4348-68-9 2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl bromide 
• 59599-14-3 2,3,5-tetra-O-benzoyl-α-D-arabinofuranosyl chloride 
• 502761-66-2 C₁₃H₁₆O₆C₁₄H₈O₂ 
• 7473-42-9 methyl tri-O-benzoyl-α-D-arabinofuranoside 

Downstream Products

• 204918-53-6 methyl 2-O-benzoyl-α-D-arabinofuranoside 
• 310880-39-8 octyl 2-O-benzoyl-α-D-arabinofuranoside 
• 1263058-09-8 3-O-acetyl-β-D-arabinofuranose 1,2,5-orthobenzoate 
• 1263058-10-1 3-O-benzoyl-β-D-arabinofuranose 1,2,5-orthobenzoate 
• 1263058-11-2 3-O-chloroacetyl-β-D-arabinofuranose 1,2,5-orthobenzoate 
• 1263058-12-3 2-chloroethyl 2-O-benzoyl-α-D-arabinofuranoside 
• 869216-48-8 phenyl 2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside 
• 1263058-31-6 phenyl 5-O-(2,3-di-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside 
• 1263058-19-0 ethyl 3-O-acetyl-2-O-benzoyl-1-thio-α-D-arabinofuranoside 
• 1263058-28-1 ethyl 5-O-(3-O-acetyl-2-O-benzoyl-α-D-arabinofuranosyl)-3-O-acetyl-2-O-benzoyl-1-thio-α-D-arabinofuranoside 
• 1263058-20-3 phenyl 3-O-acetyl-2-O-benzoyl-1-thio-α-D-arabinofuranoside 
• 1263058-29-2 phenyl 5-O-(3-O-acetyl-2-O-benzoyl-α-D-arabinofuranosyl)-3-O-acetyl-2-O-benzoyl-1-thio-α-D-arabinofuranoside 
• 1263058-21-4 ethyl 2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside 
• 1263058-30-5 ethyl 5-O-(2,3-di-O-benzoyl-α-D-arabinofuranosyl)-2,3-di-O-benzoyl-1-thio-α-D-arabinofuranoside 

Relevant academic research and scientific papers

Cyclization of β-d-arabinofuranose 1,2-methyl)orthobenzoate using magnesium bromide

Transformation of β-d-arabinofuranose 1,2-(methyl)orthobenzoate into β-d-arabinofuranose 1,2,5-orthobenzoate has been accomplished upon heating with magnesium bromide in THF. The new cyclization conditions can be applied for preparing the tricyclic 1,2,5-

Ring opening of acylated β-d-arabinofuranose 1,2,5-orthobenzoates with nucleophiles allows access to novel selectively-protected arabinofuranose building blocks

β-d-Arabinofuranose 1,2,5-orthobenzoates with 3-O-acetyl, 3-O-benzoyl, and 3-O-chloroacetyl groups were prepared in an efficient manner starting from readily available crystalline methyl 2,3,5-tri-O-benzoyl-α-d- arabinofuranoside, and ring-opening reactio

Elaboration of monoarabinofuranosidic building blocks

Nucleophilic opening of 1,2,5-orthoesters 1, 2 and 6 of D-arabinose with alcohols, ethanethiol and selenophenol was carried out under very mild conditions with Lewis acid catalysis. The reaction is stereoselective and gave α-D-arabinofuranosides in high yields. Various monoarabinofuranosides, thio-and selenoglycoside donors as well as acceptors were obtained in few steps from the opening products. These building blocks define a comprehensive system of glycosylation for the synthesis of any glycosidic linkage between arabino-furanosides. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.