(1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)imidazolidin-2-ylidene)copper(I) bromide

Base Information

• Chemical Name: (1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)imidazolidin-2-ylidene)copper(I) bromide
• CAS No.: 1426223-30-4
• Molecular Formula: C₃₇H₅₆BrCuN₄O₂
• Molecular Weight: 732.327
• Mol file: 1426223-30-4.mol

Synonyms:(1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)imidazolidin-2-ylidene)copper(I) bromide

Chemical Property of (1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)imidazolidin-2-ylidene)copper(I) bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)imidazolidin-2-ylidene)copper(I) bromide

There total 5 articles about (1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)imidazolidin-2-ylidene)copper(I) bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

copper(I) bromide dimethylsulfide complex + 1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)-4,5-dihydro-1H-imidazol-3-ium-chloride (1129711-31-4) → (1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)imidazolidin-2-ylidene)copper(I) bromide (1426223-30-4)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3gc36830k

Reference yield:

2,6-diisopropyl-4-(morpholinomethyl)aniline (86519-33-7) → (1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)imidazolidin-2-ylidene)copper(I) bromide (1426223-30-4)

Guidance literature:

Multi-step reaction with 4 steps

1: formic acid / methanol / 20 °C

2: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C

3: ammonium chloride / 120 °C

4: potassium tert-butylate / tetrahydrofuran / 24 h / 20 °C / Inert atmosphere; Schlenk technique

With lithium aluminium tetrahydride; formic acid; potassium tert-butylate; ammonium chloride; In tetrahydrofuran; methanol;

DOI:10.1039/c3gc36830k

Reference yield:

N,N'-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)ethylenediimine (1129711-19-8) → (1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)imidazolidin-2-ylidene)copper(I) bromide (1426223-30-4)

Guidance literature:

Multi-step reaction with 3 steps

1: lithium aluminium tetrahydride / tetrahydrofuran / 0 - 20 °C

2: ammonium chloride / 120 °C

3: potassium tert-butylate / tetrahydrofuran / 24 h / 20 °C / Inert atmosphere; Schlenk technique

With lithium aluminium tetrahydride; potassium tert-butylate; ammonium chloride; In tetrahydrofuran;

DOI:10.1039/c3gc36830k

upstream raw materials:

1,3-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)-4,5-dihydro-1H-imidazol-3-ium-chloride

2,6-diisopropylbenzenamine

2,6-diisopropyl-4-(morpholinomethyl)aniline

N,N'-bis(2,6-diisopropyl-4-(morpholinomethyl)phenyl)ethylenediimine