7-[(4-Methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-3-oxo-heptanoic acid methyl ester

Base Information

Chemical Name:7-[(4-Methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-3-oxo-heptanoic acid methyl ester
CAS No.:186891-44-1
Molecular Formula:C₂₃H₂₉NO₆S
Molecular Weight:447.552
Hs Code.:

Synonyms:7-[(4-Methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-3-oxo-heptanoic acid methyl ester

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Chemical Property of 7-[(4-Methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-3-oxo-heptanoic acid methyl ester

Chemical Property:

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Technology Process of 7-[(4-Methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-3-oxo-heptanoic acid methyl ester

There total 1 articles about 7-[(4-Methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-3-oxo-heptanoic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 49.0%

: 105-45-3
acetoacetic acid methyl ester

: N-(3-Bromo-propyl)-N-(4-methoxy-benzyl)-4-methyl-benzenesulfonamide

: 186891-44-1
7-[(4-Methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-3-oxo-heptanoic acid methyl ester

Guidance literature:: With n-butyllithium; sodium hydride;
DOI:10.1055/s-1997-699

Reference yield:

: 186891-44-1
7-[(4-Methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-3-oxo-heptanoic acid methyl ester

: (S)-3-Hydroxy-7-[(4-methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-heptanoic acid methyl ester

: 186891-45-2
(R)-3-Hydroxy-7-[(4-methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-heptanoic acid methyl ester

Guidance literature:: With hydrogenchloride; hydrogen; <(R)-(BINAP)RuCl2>2*NEt3; In methanol; under 10343 Torr; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1055/s-1997-699

Reference yield:

: 186891-44-1
7-[(4-Methoxy-benzyl)-(toluene-4-sulfonyl)-amino]-3-oxo-heptanoic acid methyl ester

: 186891-46-3
N-((R)-5-Hydroxy-7-oxo-octyl)-4-methyl-benzenesulfonamide

Guidance literature:: Multi-step reaction with 3 steps

1: H₂, aq. HCl / <(R)-(BINAP)RuCl₂>2*NEt₃ / methanol / 10343 Torr

2: CAN / acetonitrile; H₂O

3: 2) Bu₃SnH, AIBN / 1) THF, 2) toluene

With hydrogenchloride; ammonium cerium(IV) nitrate; 2,2'-azobis(isobutyronitrile); hydrogen; tri-n-butyl-tin hydride; <(R)-(BINAP)RuCl2>2*NEt3; In methanol; water; acetonitrile;
DOI:10.1055/s-1997-699