[2-(4-cyanophenyl)ethynyl]ferrocene

Base Information

Chemical Name:[2-(4-cyanophenyl)ethynyl]ferrocene
CAS No.:120015-71-6
Molecular Formula:C₁₉H₁₃FeN
Molecular Weight:311.166
Hs Code.:

Synonyms:[2-(4-cyanophenyl)ethynyl]ferrocene

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Chemical Property of [2-(4-cyanophenyl)ethynyl]ferrocene

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Technology Process of [2-(4-cyanophenyl)ethynyl]ferrocene

There total 3 articles about [2-(4-cyanophenyl)ethynyl]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1271-47-2
ferroceneacetylene

: 3058-39-7
4-iodobenzonitrile

: 120015-71-6
[2-(4-cyanophenyl)ethynyl]ferrocene

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine; at 100 ℃; Inert atmosphere; Schlenk technique; Microwave irradiation;
DOI:10.1002/ejoc.201402831

Reference yield: 84.0%

: 1271-47-2
ferroceneacetylene

: 623-00-7
4-bromobenzenecarbonitrile

: 120015-71-6
[2-(4-cyanophenyl)ethynyl]ferrocene

Guidance literature:: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; In further solvent(s); (N2); addn. of bromine compd. to a mixt. of iron and palladium complexesand CuI in diisopropylamine at 25°C, stirring for 16 h; evapn., dissolving in Et2O, filtration through Al2O3, concn., crystn. (-30°C); elem. anal.;
DOI:10.1016/S0022-328X(01)00904-4

Reference yield: 33.0%

: 1-ethynylferrocene

: 223562-46-7
4-(prop-1-yn-1-yl)benzonitrile

: 120015-71-6
[2-(4-cyanophenyl)ethynyl]ferrocene

Guidance literature:: With Mo(CO)6; FC₆H₄OH; In toluene; byproducts: diferrocenylethyne, NCC6H4CCC6H4CN; (Ar); addn. of molybdenum compd., phenol deriv. and propynyl deriv. to soln. of ferrocene deriv. in dry toluene, heating at 120-130°C for4 h, TLC monitoring; treatment with 1 M NaOH, extn. (CH2Cl2), washing organic phase with water and brine, drying over MgSO4, evapn., chromy. (silica gel, hexane/CHCl3(5:1)), elem. anal.;
DOI:10.1002/ejic.200800128