1,3-Propanedione, 1,3-diphenyl-, ion(1-), sodium

Base Information

• Chemical Name: 1,3-Propanedione, 1,3-diphenyl-, ion(1-), sodium
• CAS No.: 19269-14-8
• Molecular Formula: C15H11O2.Na
• Molecular Weight: 246.241
• Mol file: 19269-14-8.mol

Synonyms:

Chemical Property of 1,3-Propanedione, 1,3-diphenyl-, ion(1-), sodium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3-Propanedione, 1,3-diphenyl-, ion(1-), sodium

There total 1 articles about 1,3-Propanedione, 1,3-diphenyl-, ion(1-), sodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1,3-diphenylpropanedione (120-46-7,61346-73-4) → sodium dibenzoylmethane (19269-14-8)

Guidance literature:

With sodium; In toluene; Reflux;

DOI:10.1134/S1070363210110150

Reference yield: 95.0%

C13H24O4Si + sodium dibenzoylmethane (19269-14-8) → C26H32O3Si

Guidance literature:

With bis(1,5-cyclooctadiene)diiridium(I) dichloride; lithium chloride; (3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)-bis-((R)-1-phenyl-ethyl)-amine; In tetrahydrofuran; at 20 ℃; enantioselective reaction; Inert atmosphere;

DOI:10.1038/s41557-018-0165-x

Reference yield: 93.0%

methanol (67-56-1) + Vanadium (III) chloride-(tris-tetrahydrofuran) (131063-11-1,16997-51-6,19559-06-9) + sodium dibenzoylmethane (19269-14-8) → [V4Cl2(dibenzoylmethane(-1H))4(MeO)6]

Guidance literature:

In methanol; High Pressure; under N2 or Ar; V complex, Na salt of ligand and MeOH placed in sealed Teflon container (Parr); heated at 150°C for 12 h; cooled; filtered; crystals dried in vac.; elem. anal.;

DOI:10.1021/ic7011183

upstream raw materials:

1,3-diphenylpropanedione

Downstream raw materials:

3-benzoyl-9-methyl-2-phenyl-9H-pyrano[2,3-b]indol-4-one

2-benzoyl-1-(4-nitro-phenyl)-3-phenyl-propane-1,3-dione

N-(2'-pyridinyl)benzoylthioacetamide

2-benzoyl-1,4-diphenylbutane-1,4-dione