Technology Process of [1-H-3,5-Ph2-(C3N2)-CH2-(η5-C5H5)Fe(η5-C5H4)]
There total 1 articles about [1-H-3,5-Ph2-(C3N2)-CH2-(η5-C5H5)Fe(η5-C5H4)] which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
ethanol;
EtOH soln. of Fe compd. treated with excess N2H4*H2O (1:10 molar ratio),mixt. refluxed for 3 h; cooled to room temp., evapd., dissolved (CH2Cl2), chromd. (SiO2, CH2Cl2), evapd., dried (vac., 2 d), elem. anal.;
DOI:10.1016/j.jorganchem.2009.07.006
- Guidance literature:
-
With
benzyltriethylammonium chloride;
In
sodium hydroxide; toluene;
aq. NaOH; aq. NaOH added to toluene soln. of Fe compd. (1.91 mmol) and benzyltriethylammonium chloride (0.95 mmol), CH3I (3.82 mmol) added dropwise, mixt. stirred at room temp. for 24 h; H2O added, extd. (CH2Cl2), org. layer dried (Na2SO4), evapd., dissolved (CH2Cl2), chromd. (Al2O3, CH2Cl2), evapd., dried (vac., 2 d), elem. anal.;
DOI:10.1016/j.jorganchem.2009.07.006
- Guidance literature:
-
With
N-benzyl-N,N,N-triethylammonium chloride; sodium hydroxide;
In
water; toluene;
at 96.84 ℃;
for 24h;
DOI:10.1002/ejic.201500520
