ETHYL BETA-D-THIOGLUCOSIDE

Base Information

• Chemical Name: ETHYL BETA-D-THIOGLUCOSIDE
• CAS No.: 7473-36-1
• Molecular Formula: C₈H₁₆O₅S
• Molecular Weight: 224.278
• Mol file: 7473-36-1.mol

Synonyms:Glucopyranoside,ethyl 1-thio-, b-D-(8CI);Ethyl 1-thio-b-D-glucopyranoside;NSC 400275;

Chemical Property of ETHYL BETA-D-THIOGLUCOSIDE

Chemical Property:

• Vapor Pressure: 1.28E-09mmHg at 25°C
• Melting Point: 87-89oC
• Refractive Index: 1.592
• Boiling Point: 440.8 °C at 760 mmHg
• PKA: 13.00±0.70(Predicted)
• Flash Point: 220.4 °C
• PSA: 115.45000
• Density: 1.43 g/cm³
• LogP: -1.46060
• Storage Temp.: −20°C
• Solubility.: Dichloromethane, Methanol

Purity/Quality:

98%, ^*data from raw suppliers

(2S,3R,4S,5S,6R)-2-(Ethylthio)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ETHYL BETA-D-THIOGLUCOSIDE

There total 35 articles about ETHYL BETA-D-THIOGLUCOSIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

S-ethyl 2,3,4,6-tetra-O-acetyl-1-deoxy-1-thio-α-D-mannopyranoside (32934-24-0,41670-79-5,52645-73-5,55722-49-1,79389-52-9,99031-86-4,125354-48-5,126187-25-5) → ethyl 1-thio-α-D-mannopyranoside (7473-36-1,13533-58-9,36400-88-1,56245-60-4,73494-52-7,73804-33-8,128946-17-8,686299-00-3)

Guidance literature:

With sodium methylate; In methanol;

DOI:10.1016/S0040-4039(00)01497-0

Reference yield: 100.0%

ethyl 2,3,4,6-tetra-O-acetyl-1-thio-α-D-glycopyranoside (32934-24-0,41670-79-5,52645-73-5,55722-49-1,79389-52-9,99031-86-4,125354-48-5,126187-25-5) → (2R,3R,4S,5S,6R)-2-Ethylsulfanyl-6-hydroxymethyl-tetrahydro-pyran-3,4,5-triol (7473-36-1,13533-58-9,36400-88-1,56245-60-4,73494-52-7,73804-33-8,128946-17-8,686299-00-3)

Guidance literature:

With methanol; sodium methylate; for 20h; Ambient temperature;

DOI:10.1016/0957-4166(96)00066-3

Reference yield: 100.0%

ethyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside (32934-24-0,41670-79-5,52645-73-5,55722-49-1,79389-52-9,99031-86-4,125354-48-5,126187-25-5) → ethyl 1-thio-β-D-glucopyranoside (7473-36-1,13533-58-9,36400-88-1,56245-60-4,73494-52-7,73804-33-8,128946-17-8,686299-00-3)

Guidance literature:

With methanol; sodium methylate; for 20h; Ambient temperature;

DOI:10.1016/0957-4166(96)00066-3

upstream raw materials:

ethyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside

ethanethiol

β-D-glucose pentaacetate

ethyl iodide

Downstream raw materials:

ethyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside

ethyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside

ethyl 4,6-O-benzylidene-1-thio-β-D-glucopyranoside

1-deoxy-1-(S-ethyl)-2,3,4,6-tetra-O-benzyl-β-D-glucopyranoside