4-nitrophenyl 2-pyridyl sulfoxide

Base Information

• Chemical Name: 4-nitrophenyl 2-pyridyl sulfoxide
• CAS No.: 1279130-14-1
• Molecular Formula: C₁₁H₈N₂O₃S
• Molecular Weight: 248.262
• Mol file: 1279130-14-1.mol

Synonyms:4-nitrophenyl 2-pyridyl sulfoxide

Chemical Property of 4-nitrophenyl 2-pyridyl sulfoxide

Chemical Property:

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Technology Process of 4-nitrophenyl 2-pyridyl sulfoxide

There total 1 articles about 4-nitrophenyl 2-pyridyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

2-((4-nitrophenyl)thio)pyridine (73322-01-7) → 4-nitrophenyl 2-pyridyl sulfoxide (1279130-14-1)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 0 ℃;

DOI:10.1002/adsc.201000941

Reference yield: 47.0%

4-nitrophenyl 2-pyridyl sulfoxide (1279130-14-1) + dibenzoyl peroxide (94-36-0) → C17H12N2O3S

Guidance literature:

With palladium diacetate; acetic acid; In acetonitrile; at 80 ℃; for 16h; regioselective reaction; Inert atmosphere;

DOI:10.1039/c6ob02040b

Reference yield: 33.0%

4-nitrophenyl 2-pyridyl sulfoxide (1279130-14-1) + 1-bromo-2-(triisopropylsilyl)acetylene (111409-79-1) → (R)-2-((4-nitro-2-((triisopropylsilyl)ethynyl)phenyl)sulfinyl)pyridine + (S)-2-((4-nitrophenyl)sulfinyl)pyridine + 2-((4-nitrophenyl)sulfinyl)pyridine

Guidance literature:

With palladium diacetate; silver carbonate; L-Pyroglutamic acid; In tert-Amyl alcohol; toluene; at 60 ℃; for 48h; enantioselective reaction; Schlenk technique;

DOI:10.1021/acs.orglett.1c02918

upstream raw materials:

2-((4-nitrophenyl)thio)pyridine