2-Bromobenzophenone

Base Information

• Chemical Name: 2-Bromobenzophenone
• CAS No.: 13047-06-8
• Molecular Formula: C13H9BrO
• Molecular Weight: 261.118
• Hs Code.: 29143990
• European Community (EC) Number: 673-539-8
• DSSTox Substance ID: DTXSID20370777
• Nikkaji Number: J338.569H
• Wikidata: Q82157940
• Mol file: 13047-06-8.mol

Synonyms:2-Bromobenzophenone;13047-06-8;(2-Bromophenyl)(phenyl)methanone;(2-bromophenyl)-phenylmethanone;bromobenzophenone;Methanone, (bromophenyl)phenyl-;MFCD00032462;Methanone,(2-bromophenyl)phenyl-;ChemDiv2_000041;2-Bromobenzophenone, 95%;SCHEMBL723657;(2-Bromophenyl)phenylmethanone;IFLab1_003189;DTXSID20370777;ABEVIHIQUUXDMS-UHFFFAOYSA-N;HMS1369B19;HMS1421A21;Methanone, (2-bromophenyl)phenyl-;AKOS000115368;AM803148;DS-18156;SY050367;B3937;CS-0037116;FT-0636780;EN300-01076;A806089;AE-641/02445046;SR-01000403843;J-500669;SR-01000403843-1;Z87001555;F0722-1800;(2-bromophenyl)-phenyl-methanone

Chemical Property of 2-Bromobenzophenone

Chemical Property:

• Vapor Pressure: 6.09E-05mmHg at 25°C
• Melting Point: 42 °C
• Refractive Index: n20/D 1.6254
• Boiling Point: 345.6 °C at 760 mmHg
• Flash Point: 80.4 °C
• PSA: 17.07000
• Density: 1.421 g/cm³
• LogP: 3.68010
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: soluble in Toluene
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 259.98368
• Heavy Atom Count: 15
• Complexity: 221

Purity/Quality:

97% ^*data from raw suppliers

2-Bromobenzophenone ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi;N
• Hazard Codes: Xi,N
• Statements: 51/53
• Safety Statements: 61

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=O)C2=CC=CC=C2Br

Technology Process of 2-Bromobenzophenone

There total 62 articles about 2-Bromobenzophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-bromobenzoic acid chloride (7154-66-7) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → o-bromobenzophenone (13047-06-8)

Guidance literature:

With aluminum (III) chloride;

DOI:10.1016/j.dyepig.2012.05.017

Reference yield: 93.0%

(2-bromophenyl)phenylmethanol (59142-47-1) → o-bromobenzophenone (13047-06-8)

Guidance literature:

With silica gel; pyridinium chlorochromate; In dichloromethane; at 20 ℃;

DOI:10.1002/anie.202002289

Reference yield: 92.0%

sodium tetraphenyl borate (143-66-8) + 2-bromobenzoic acid chloride (7154-66-7) → o-bromobenzophenone (13047-06-8)

Guidance literature:

With sodium carbonate; palladium diacetate; In acetone; at 20 ℃; for 5h;

DOI:10.1023/B:RUCB.0000030812.95602.0a

upstream raw materials:

bromobenzene

benzoyl chloride

2-bromobenzoic acid chloride

benzene

Downstream raw materials:

1-bromo-2-(1-phenylpropen-1-yl)benzene

1,1,2,2-tetraphenylethylene

2,2'-dibenzoylbiphenyl

2-benzyl-1-bromobenzene