1-(((S)-4',5'-dihydro-2'-(1-adamantyl)-4'-oxazolyl)ethyl)-3-(3,5-ditert-butyl-4-methoxyl-phenyl)imidazolium iodide

Base Information

Chemical Name:1-(((S)-4',5'-dihydro-2'-(1-adamantyl)-4'-oxazolyl)ethyl)-3-(3,5-ditert-butyl-4-methoxyl-phenyl)imidazolium iodide
CAS No.:496067-64-2
Molecular Formula:C₃₃H₄₈N₃O₂*I
Molecular Weight:645.668
Hs Code.:

Synonyms:1-(((S)-4',5'-dihydro-2'-(1-adamantyl)-4'-oxazolyl)ethyl)-3-(3,5-ditert-butyl-4-methoxyl-phenyl)imidazolium iodide

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Chemical Property of 1-(((S)-4',5'-dihydro-2'-(1-adamantyl)-4'-oxazolyl)ethyl)-3-(3,5-ditert-butyl-4-methoxyl-phenyl)imidazolium iodide

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Technology Process of 1-(((S)-4',5'-dihydro-2'-(1-adamantyl)-4'-oxazolyl)ethyl)-3-(3,5-ditert-butyl-4-methoxyl-phenyl)imidazolium iodide

There total 6 articles about 1-(((S)-4',5'-dihydro-2'-(1-adamantyl)-4'-oxazolyl)ethyl)-3-(3,5-ditert-butyl-4-methoxyl-phenyl)imidazolium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1516-96-7
4-bromo-2,6-di-tert-butylanisole

: 496067-64-2
1-(((S)-4',5'-dihydro-2'-(1-adamantyl)-4'-oxazolyl)ethyl)-3-(3,5-ditert-butyl-4-methoxyl-phenyl)imidazolium iodide

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / Cs₂CO₃; dba; 1,10-phenanthroline / Cu(I)OTf / xylene / 36 h / 125 °C

2: dimethylformamide / 12 h / 80 °C

With 1,10-Phenanthroline; caesium carbonate; 1,5-diphenyl-1,4-pentadiene-3-one; copper(I) triflate; In N,N-dimethyl-formamide; xylene;
DOI:10.1021/ja028142b

Reference yield:

: 2094-72-6
1-Adamantanecarbonyl chloride

: 496067-64-2
1-(((S)-4',5'-dihydro-2'-(1-adamantyl)-4'-oxazolyl)ethyl)-3-(3,5-ditert-butyl-4-methoxyl-phenyl)imidazolium iodide

Guidance literature:: Multi-step reaction with 5 steps

1: 95 percent / Et₃N / CH₂Cl₂ / 12 h / 25 °C

2: 60 percent / NaBH₄ / ethanol / 12 h / 25 °C

3: 80 percent / Et₃N / CH₂Cl₂ / 24 h / 0 - 25 °C

4: 89 percent / KI / acetone / 4 h / 56 °C

5: dimethylformamide / 12 h / 80 °C

With sodium tetrahydroborate; triethylamine; potassium iodide; In ethanol; dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.1021/ja028142b

Reference yield:

: 496067-58-4
Adamantane-1-carboxylic acid ((S)-3-hydroxy-1-hydroxymethyl-propyl)-amide

: 496067-64-2
1-(((S)-4',5'-dihydro-2'-(1-adamantyl)-4'-oxazolyl)ethyl)-3-(3,5-ditert-butyl-4-methoxyl-phenyl)imidazolium iodide

Guidance literature:: Multi-step reaction with 3 steps

1: 80 percent / Et₃N / CH₂Cl₂ / 24 h / 0 - 25 °C

2: 89 percent / KI / acetone / 4 h / 56 °C

3: dimethylformamide / 12 h / 80 °C

With triethylamine; potassium iodide; In dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.1021/ja028142b