α-((dimethylphenylsilyl)oxy)hexyltributylstannane

Base Information

Chemical Name:α-((dimethylphenylsilyl)oxy)hexyltributylstannane
CAS No.:125950-70-1
Molecular Formula:C₂₆H₅₀OSiSn
Molecular Weight:525.478
Hs Code.:

Synonyms:α-((dimethylphenylsilyl)oxy)hexyltributylstannane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of α-((dimethylphenylsilyl)oxy)hexyltributylstannane

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Technology Process of α-((dimethylphenylsilyl)oxy)hexyltributylstannane

There total 1 articles about α-((dimethylphenylsilyl)oxy)hexyltributylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4226-01-1
tri-n-butyltin lithium

: 125950-79-0,117438-47-8,125950-78-9
1-(tributylstannyl)hexan-1-ol

: 768-33-2
phenyldimethylsilyl chloride

: 125950-70-1
α-((dimethylphenylsilyl)oxy)hexyltributylstannane

Guidance literature:: With dmap; N-ethyl-N,N-diisopropylamine; In dichloromethane; dissoln. of stannyl-compd. in CH2Cl2, cooling to 0°C, addn. of amine and pyridine, followed by dropwise addn. of silane, gradually warming to room temp., stirring for 48 h; diluting with petroleum ether, washing with satured aq. NaCl, drying over anhyd. Na2SO4, removing solvents under reduced pressure yields crude stannyl silyl ether;
DOI:10.1021/ja00162a048

Reference yield:

: 125950-70-1
α-((dimethylphenylsilyl)oxy)hexyltributylstannane

: 125950-71-2
dimethylphenyl(α-hydroxyhexyl)silane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; byproducts: Sn(Bu)4; dropwise addn. of n-BuLi in hexane to stannyl silyl ether in dry THF (under Ar, -78°C, via syringe), stirring (-78°C, 15 min), quenching at -78°C by rapid addn. of water; warming to room temp., extn. using petroleum ether, flash chromy. on silica gel, eluation of tetraalkylstannane (hexane), eluation of product (ethyl acetate/hexane);
DOI:10.1021/ja00162a048