[Pd(COMe)Cl(1,3-bis(diphenylphosphino)propane)]

Base Information

Chemical Name:[Pd(COMe)Cl(1,3-bis(diphenylphosphino)propane)]
CAS No.:139168-09-5
Molecular Formula:C₂₉H₂₉ClOP₂Pd
Molecular Weight:597.369
Hs Code.:

Synonyms:[Pd(COMe)Cl(1,3-bis(diphenylphosphino)propane)]

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Chemical Property of [Pd(COMe)Cl(1,3-bis(diphenylphosphino)propane)]

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Technology Process of [Pd(COMe)Cl(1,3-bis(diphenylphosphino)propane)]

There total 2 articles about [Pd(COMe)Cl(1,3-bis(diphenylphosphino)propane)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 139168-06-2
[PdCl(CH₃)(bis(diphenylphosphino)propane)]

: 201230-82-2
carbon monoxide

: 139168-09-5
[Pd(COMe)Cl(1,3-bis(diphenylphosphino)propane)]

Guidance literature:: In dichloromethane; under Ar, Pd complex was dissolved in CH2Cl2 at 25°C with stirring, CO was added for 30 min and stirring was continued for 2 h; the soln. was filtered through Celite, the solvent was removed in vac.,the residue was washed with pentane; elem. anal.;
DOI:10.1021/ja994251n

Reference yield:

: 139168-06-2
[PdCl(CH₃)(bis(diphenylphosphino)propane)]

: 139168-09-5
[Pd(COMe)Cl(1,3-bis(diphenylphosphino)propane)]

Guidance literature:: With carbon monoxide; In dichloromethane-d2; gentle stream of CO passed through soln. of the Pd complex in CD2Cl2 (NMR tube, 0.75 h); isolation was not successfull; detn. by (1)H, (31)P-NMR, IR;
DOI:10.1021/om00040a034

Reference yield:

: 26042-64-8
silver hexafluoroantimonate

: 139168-09-5
[Pd(COMe)Cl(1,3-bis(diphenylphosphino)propane)]

: 74-85-1
ethene

: [(1,3-bis(diphenylphosphino)propane)Pd(CH₂CH₂COCH₃)][sbF₆]

Guidance literature:: In dichloromethane-d2; AgSbF6 and CDCl2F/CD2Cl2 (1/1) were added to Pd complex in sapphire tubeat -130°C under N2; pressurized with C2H4 (15 bar) at -130.degre e.C; warmed to -117°C; NMR monitoring;
DOI:10.1021/om020461o