c-4-pivaloyloxymethyl-4-((Z)-4-trifluoromethanesulfonyloxy-3-butenyl)-2,5-cyclohexen-r-1-ol

Base Information

Chemical Name:c-4-pivaloyloxymethyl-4-((Z)-4-trifluoromethanesulfonyloxy-3-butenyl)-2,5-cyclohexen-r-1-ol
CAS No.:152327-06-5
Molecular Formula:C₁₇H₂₃F₃O₆S
Molecular Weight:412.427
Hs Code.:

Synonyms:c-4-pivaloyloxymethyl-4-((Z)-4-trifluoromethanesulfonyloxy-3-butenyl)-2,5-cyclohexen-r-1-ol

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Chemical Property of c-4-pivaloyloxymethyl-4-((Z)-4-trifluoromethanesulfonyloxy-3-butenyl)-2,5-cyclohexen-r-1-ol

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Technology Process of c-4-pivaloyloxymethyl-4-((Z)-4-trifluoromethanesulfonyloxy-3-butenyl)-2,5-cyclohexen-r-1-ol

There total 2 articles about c-4-pivaloyloxymethyl-4-((Z)-4-trifluoromethanesulfonyloxy-3-butenyl)-2,5-cyclohexen-r-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

: 152327-10-1
4-pivaloyloxymethyl-4-((Z)-4-trifluoromethanesulfonyloxy-3-butenyl)-2,5-cyclohexadien-1-one

: 152377-33-8
2,2-Dimethyl-propionic acid 4-hydroxy-1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester

: 152327-06-5
c-4-pivaloyloxymethyl-4-((Z)-4-trifluoromethanesulfonyloxy-3-butenyl)-2,5-cyclohexen-r-1-ol

Guidance literature:: With sodium tetrahydroborate; cerium(III) chloride; In methanol; at -78 ℃; for 1h;

Reference yield:

: 152327-05-4
2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester

: 152327-06-5
c-4-pivaloyloxymethyl-4-((Z)-4-trifluoromethanesulfonyloxy-3-butenyl)-2,5-cyclohexen-r-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 71 percent / CrO₃, DMP / CH₂Cl₂ / 1 h / -20 °C

2: 61 percent / NaBH₄, CeCl₃ / methanol / 1 h / -78 °C

With chromium(VI) oxide; sodium tetrahydroborate; cerium(III) chloride; phthalic acid dimethyl ester; In methanol; dichloromethane;
DOI:10.1016/S0040-4039(00)60532-4

Reference yield: 36.0%

: 152327-06-5
c-4-pivaloyloxymethyl-4-((Z)-4-trifluoromethanesulfonyloxy-3-butenyl)-2,5-cyclohexen-r-1-ol

: 2,2-Dimethyl-propionic acid 1-but-3-enyl-4-oxo-cyclohexa-2,5-dienylmethyl ester

: 152327-07-6
(1R,6S)-6-pivaloyloxymethylbicyclo<4.4.0>deca-4,9-dien-3-one

Guidance literature:: With potassium carbonate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; In benzene; at 60 ℃; for 36h;