2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester

Base Information

Chemical Name:2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester
CAS No.:152327-05-4
Molecular Formula:C₁₇H₂₃F₃O₅S
Molecular Weight:396.428
Hs Code.:

Synonyms:2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester

Suppliers and Price of 2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester

There total 5 articles about 2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 3282-30-2
pivaloyl chloride

: 142389-68-2
Trifluoro-methanesulfonic acid (Z)-4-(1-hydroxymethyl-cyclohexa-2,5-dienyl)-but-1-enyl ester

: 152327-05-4
2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester

Guidance literature:: With pyridine; dmap; In dichloromethane;
DOI:10.1016/S0040-4039(00)92251-2

Reference yield:

: 30889-20-4
methyl cyclohexa-2,5-diene-1-carboxylate

: 152327-05-4
2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: 1) LDA / 1) THF, 0 deg C, 2) 0 deg C

2: 100 percent / TsOH / acetone / Ambient temperature

3: 63 percent / 2,6-di-tert-butylpyridine / 1,2-dichloro-ethane / 0.33 h / Heating

4: 85 percent / LiAlH₄ / diethyl ether / -78 °C

5: 98 percent / pyridine, DMAP / CH₂Cl₂

With pyridine; dmap; lithium aluminium tetrahydride; 2,6-di-tert-butyl-pyridine; toluene-4-sulfonic acid; lithium diisopropyl amide; In diethyl ether; dichloromethane; 1,2-dichloro-ethane; acetone;
DOI:10.1016/S0040-4039(00)92251-2

Reference yield:

: 142389-63-7
methyl 1-(4-oxobutyl)-2,5-cyclohexadiene-1-carboxylate

: 152327-05-4
2,2-Dimethyl-propionic acid 1-((Z)-4-trifluoromethanesulfonyloxy-but-3-enyl)-cyclohexa-2,5-dienylmethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 63 percent / 2,6-di-tert-butylpyridine / 1,2-dichloro-ethane / 0.33 h / Heating

2: 85 percent / LiAlH₄ / diethyl ether / -78 °C

3: 98 percent / pyridine, DMAP / CH₂Cl₂

With pyridine; dmap; lithium aluminium tetrahydride; 2,6-di-tert-butyl-pyridine; In diethyl ether; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1016/S0040-4039(00)92251-2