(2R,3S,4R)-2-Allyloxymethyl-3,4-bis-benzyloxy-5-methoxy-tetrahydro-furan

Base Information

Chemical Name:(2R,3S,4R)-2-Allyloxymethyl-3,4-bis-benzyloxy-5-methoxy-tetrahydro-furan
CAS No.:220509-08-0
Molecular Formula:C₂₃H₂₈O₅
Molecular Weight:384.472
Hs Code.:

Synonyms:(2R,3S,4R)-2-Allyloxymethyl-3,4-bis-benzyloxy-5-methoxy-tetrahydro-furan

Suppliers and Price of (2R,3S,4R)-2-Allyloxymethyl-3,4-bis-benzyloxy-5-methoxy-tetrahydro-furan

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2R,3S,4R)-2-Allyloxymethyl-3,4-bis-benzyloxy-5-methoxy-tetrahydro-furan

Chemical Property:

Purity/Quality:

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Technology Process of (2R,3S,4R)-2-Allyloxymethyl-3,4-bis-benzyloxy-5-methoxy-tetrahydro-furan

There total 1 articles about (2R,3S,4R)-2-Allyloxymethyl-3,4-bis-benzyloxy-5-methoxy-tetrahydro-furan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 100-39-0
benzyl bromide

: 220509-07-9
(3R,4R,5R)-5-Allyloxymethyl-4-benzyloxy-2-methoxy-tetrahydro-furan-3-ol

: 220509-08-0
(2R,3S,4R)-2-Allyloxymethyl-3,4-bis-benzyloxy-5-methoxy-tetrahydro-furan

Guidance literature:: With tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran;

Reference yield:

: 220509-08-0
(2R,3S,4R)-2-Allyloxymethyl-3,4-bis-benzyloxy-5-methoxy-tetrahydro-furan

: 220509-21-7
((3S,4S,5R)-4,5-Bis-benzyloxy-6-methoxy-tetrahydro-pyran-3-yl)-carbamic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) t-BuOK; 2.) fOrmic acid / 1.) DMSO, 100 deg C, 20 min; 2.) Et₂O

2: 71 percent / HCl / CHCl₃

3: DMAP, Et₃N / CH₂Cl₂ / 0 °C

4: CH₂Cl₂ / 5 h / 0 °C

5: Hg(ClO₄)2 / 1 h

6: HCl / methanol

7: 91 percent / NaN₃ / dimethylformamide / 10 h / 120 °C

8: 93 percent / H₂ / Pd/Al₂O₃ / ethyl acetate

With hydrogenchloride; dmap; formic acid; sodium azide; mercury(II) perchlorate; potassium tert-butylate; hydrogen; triethylamine; palladium/alumina; In methanol; dichloromethane; chloroform; ethyl acetate; N,N-dimethyl-formamide;

Reference yield:

: 220509-08-0
(2R,3S,4R)-2-Allyloxymethyl-3,4-bis-benzyloxy-5-methoxy-tetrahydro-furan

: 220509-17-1
Methanesulfonic acid (3R,4R,5R)-4,5-bis-benzyloxy-6-methoxy-tetrahydro-pyran-3-yl ester

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) t-BuOK; 2.) fOrmic acid / 1.) DMSO, 100 deg C, 20 min; 2.) Et₂O

2: 71 percent / HCl / CHCl₃

3: DMAP, Et₃N / CH₂Cl₂ / 0 °C

4: CH₂Cl₂ / 5 h / 0 °C

5: Hg(ClO₄)2 / 1 h

6: HCl / methanol

With hydrogenchloride; dmap; formic acid; mercury(II) perchlorate; potassium tert-butylate; triethylamine; In methanol; dichloromethane; chloroform;