trans-(+/-)-(1,1-Dimethylethyl)dimethyl<2-methyl-4-<(phenylmethoxy)methyl>-3-cyclopenten-1-yl>silane

Base Information

Chemical Name:trans-(+/-)-(1,1-Dimethylethyl)dimethyl<2-methyl-4-<(phenylmethoxy)methyl>-3-cyclopenten-1-yl>silane
CAS No.:115802-79-4
Molecular Formula:C₂₀H₃₂O₂Si
Molecular Weight:332.558
Hs Code.:

Synonyms:trans-(+/-)-(1,1-Dimethylethyl)dimethyl<2-methyl-4-<(phenylmethoxy)methyl>-3-cyclopenten-1-yl>silane

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Chemical Property of trans-(+/-)-(1,1-Dimethylethyl)dimethyl<2-methyl-4-<(phenylmethoxy)methyl>-3-cyclopenten-1-yl>silane

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Technology Process of trans-(+/-)-(1,1-Dimethylethyl)dimethyl<2-methyl-4-<(phenylmethoxy)methyl>-3-cyclopenten-1-yl>silane

There total 4 articles about trans-(+/-)-(1,1-Dimethylethyl)dimethyl<2-methyl-4-<(phenylmethoxy)methyl>-3-cyclopenten-1-yl>silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 100-39-0
benzyl bromide

: 115802-75-0
trans-(+/-)-4-<<(1,1-Dimethylethyl)dimethylsilyl>oxy>-3-methyl-1-cyclopentene-1-methanol

: 115802-79-4
trans-(+/-)-(1,1-Dimethylethyl)dimethyl<2-methyl-4-<(phenylmethoxy)methyl>-3-cyclopenten-1-yl>silane

Guidance literature:: With sodium hydride; sodium iodide; In 1,2-dimethoxyethane;
DOI:10.1039/c39880000217

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 115802-79-4
trans-(+/-)-(1,1-Dimethylethyl)dimethyl<2-methyl-4-<(phenylmethoxy)methyl>-3-cyclopenten-1-yl>silane

Guidance literature:: Multi-step reaction with 5 steps

1: 90 percent / 4-N,N-dimethylaminopyridine / dimethylformamide

2: 1.) O₃, 2.) H₂ / 2.) Pd/C / 2.) MeOH

3: dibenzylammonium trifluoroacetate / CH₂Cl₂

4: 95 percent / Li(O-t-Bu)3H

5: 90 percent / NaH, NaI / 1,2-dimethoxy-ethane

With dmap; hydrogen; sodium hydride; ozone; lithium tri-t-butoxyaluminum hydride; sodium iodide; dibenzylammonium trifluoroacetate salt; palladium on activated charcoal; In 1,2-dimethoxyethane; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/c39880000217

Reference yield:

: 135840-35-6
(R*,S*)-(+/-)-3-<<(1,1-Dimethylethyl)dimethylsilyl>oxy>-2-methylhexan-1.6-dial

: 115802-79-4
trans-(+/-)-(1,1-Dimethylethyl)dimethyl<2-methyl-4-<(phenylmethoxy)methyl>-3-cyclopenten-1-yl>silane

Guidance literature:: Multi-step reaction with 3 steps

1: dibenzylammonium trifluoroacetate / CH₂Cl₂

2: 95 percent / Li(O-t-Bu)3H

3: 90 percent / NaH, NaI / 1,2-dimethoxy-ethane

With sodium hydride; lithium tri-t-butoxyaluminum hydride; sodium iodide; dibenzylammonium trifluoroacetate salt; In 1,2-dimethoxyethane; dichloromethane;
DOI:10.1039/c39880000217