Dithiocarbonic acid O-phenyl S-methyl ester

Base Information

• Chemical Name: Dithiocarbonic acid O-phenyl S-methyl ester
• CAS No.: 13509-30-3
• Molecular Formula: C₈H₈OS₂
• Molecular Weight: 184.283
• Mol file: 13509-30-3.mol

Synonyms:O-phenyl, S-methyl dithiocarbonate

Chemical Property of Dithiocarbonic acid O-phenyl S-methyl ester

Chemical Property:

• Boiling Point: 100 °C(Press: 1 Torr)
• Density: 1.237±0.06 g/cm3(Predicted)

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Dithiocarbonic acid O-phenyl S-methyl ester

There total 7 articles about Dithiocarbonic acid O-phenyl S-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

carbon disulfide (75-15-0,12122-00-8) + methyl iodide (74-88-4) + phenol (108-95-2,27073-41-2) → O-phenyl, S-methyl dithiocarbonate (13509-30-3)

Guidance literature:

phenol; With sodium hydroxide; In tetrahydrofuran; at 20 ℃; for 0.166667h;

carbon disulfide; In tetrahydrofuran; at 0 ℃; for 0.166667h;

methyl iodide; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1055/s-0036-1590811

Reference yield: 92.0%

3-methyl-1-(methyldithiocarbonyl)imidazolium iodide + phenol (108-95-2,27073-41-2) → O-phenyl, S-methyl dithiocarbonate (13509-30-3)

Guidance literature:

With triethylamine; In acetonitrile; at 0 ℃; for 1h; Inert atmosphere;

DOI:10.1021/acs.joc.9b02717

Reference yield:

sodium phenoxide (139-02-6) → O-phenyl, S-methyl dithiocarbonate (13509-30-3)

Guidance literature:

Multi-step reaction with 2 steps

1: microwave irradiation

2: CS₂ / 1 h / Heating

In carbon disulfide;

DOI:10.1080/104265090921173

upstream raw materials:

methyl chlorodithioformate

phenol

carbon disulfide

methylene chloride