4'-(2-{2-[2-(tosylate-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine

Base Information

Chemical Name:4'-(2-{2-[2-(tosylate-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine
CAS No.:1416235-89-6
Molecular Formula:C₃₀H₃₃N₃O₇S
Molecular Weight:579.674
Hs Code.:

Synonyms:4'-(2-{2-[2-(tosylate-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine

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Chemical Property of 4'-(2-{2-[2-(tosylate-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine

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Technology Process of 4'-(2-{2-[2-(tosylate-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine

There total 2 articles about 4'-(2-{2-[2-(tosylate-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1416235-86-3
4'-{2-{2-[2-(2-hydroxyethoxy)ethoxy]ethoxy}ethoxy}-2,2':6′,2''-terpyridine

: 98-59-9
p-toluenesulfonyl chloride

: 1416235-89-6
4'-(2-{2-[2-(tosylate-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine

Guidance literature:: 4'-{2-{2-[2-(2-hydroxyethoxy)ethoxy]ethoxy}ethoxy}-2,2':6′,2''-terpyridine; With silver(l) oxide; In dichloromethane; at 0 ℃; for 0.5h;

p-toluenesulfonyl chloride; With potassium iodide; In dichloromethane; at 0 - 20 ℃; for 25h;
DOI:10.1039/c2ob26587g

Reference yield:

: 112-60-7
Tetraethylene glycol

: 1416235-89-6
4'-(2-{2-[2-(tosylate-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine

Guidance literature:: Multi-step reaction with 3 steps

1.1: silver(l) oxide / dichloromethane

1.2: 12 h / 0 - 20 °C

2.1: potassium carbonate / N,N-dimethyl-formamide / 1 h / 70 °C

2.2: 72 h / 70 °C

3.1: silver(l) oxide / dichloromethane / 0.5 h / 0 °C

3.2: 25 h / 0 - 20 °C

With potassium carbonate; silver(l) oxide; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1039/c2ob26587g

Reference yield: 56.0%

: 1292784-06-5
5-(3-hydroxyphenyl)-10,15,20-tris(p-tolyl)porphyrinatozinc(II)

: 1416235-89-6
4'-(2-{2-[2-(tosylate-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine

: 4'-(2-{2-[2-(zinc(II)-5-[m-hydroxyphenyl]-10,15,20-tris-[p-tolyl]porphyrin-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine

Guidance literature:: 5-(3-hydroxyphenyl)-10,15,20-tris(p-tolyl)porphyrinatozinc(II); With potassium carbonate; In N,N-dimethyl-formamide; at 70 ℃; for 1h;

4'-(2-{2-[2-(tosylate-2-ethoxy)ethoxy]ethoxy}ethoxy)-2,2':6',2''-terpyridine; In N,N-dimethyl-formamide; at 70 ℃; for 72h;
DOI:10.1039/c2ob26587g