3-Chloro-benzoic acid methylsulfanyl-bis-trimethylsilanyl-methyl ester

Base Information

Chemical Name:3-Chloro-benzoic acid methylsulfanyl-bis-trimethylsilanyl-methyl ester
CAS No.:111277-61-3
Molecular Formula:C₁₅H₂₅ClO₂SSi₂
Molecular Weight:361.052
Hs Code.:

Synonyms:3-Chloro-benzoic acid methylsulfanyl-bis-trimethylsilanyl-methyl ester

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Chemical Property of 3-Chloro-benzoic acid methylsulfanyl-bis-trimethylsilanyl-methyl ester

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Technology Process of 3-Chloro-benzoic acid methylsulfanyl-bis-trimethylsilanyl-methyl ester

There total 4 articles about 3-Chloro-benzoic acid methylsulfanyl-bis-trimethylsilanyl-methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 31704-09-3
tris(trimethylsilyl)methyl methyl sulfide

: 42606-61-1
bis(trimethylsilyl)ketone

: 111313-23-6
Bis-methylsulfanyl-bis-trimethylsilanyl-methane

: 111277-61-3
3-Chloro-benzoic acid methylsulfanyl-bis-trimethylsilanyl-methyl ester

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 ℃; for 0.166667h;
DOI:10.1016/S0040-4039(00)85379-4

Reference yield: 45.0%

: 31704-09-3
tris(trimethylsilyl)methyl methyl sulfide

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: 42606-61-1
bis(trimethylsilyl)ketone

: 111313-23-6
Bis-methylsulfanyl-bis-trimethylsilanyl-methane

: 111277-61-3
3-Chloro-benzoic acid methylsulfanyl-bis-trimethylsilanyl-methyl ester

Guidance literature:: In dichloromethane; at -78 ℃; for 0.166667h;
DOI:10.1016/S0040-4039(00)85379-4

Reference yield:

: 31704-08-2
bis(trimethylsilyl)methylthio-methane

: 111277-61-3
3-Chloro-benzoic acid methylsulfanyl-bis-trimethylsilanyl-methyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) n-BuLi / 1.) -60 grad C 30 min, rt 3 h, ether, hexane, 2) -50 grad C, then rt overnight

2: MCPBA / CH₂Cl₂ / 0.17 h / -78 °C

With n-butyllithium; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1016/S0040-4039(00)85379-4