1L-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-2,3,4,5-cyclohexantetrol

Base Information

Chemical Name:1L-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-2,3,4,5-cyclohexantetrol
CAS No.:105017-72-9
Molecular Formula:C₂₈H₃₂O₅
Molecular Weight:448.559
Hs Code.:

Synonyms:1L-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-2,3,4,5-cyclohexantetrol

Suppliers and Price of 1L-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-2,3,4,5-cyclohexantetrol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1L-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-2,3,4,5-cyclohexantetrol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1L-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-2,3,4,5-cyclohexantetrol

There total 6 articles about 1L-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-2,3,4,5-cyclohexantetrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 1233208-86-0
5a-carba-2,3,4,6-tetra-O-benzyl-α-L-idopyranose

: 105017-72-9
1L-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-2,3,4,5-cyclohexantetrol

Guidance literature:: 5a-carba-2,3,4,6-tetra-O-benzyl-α-L-idopyranose; With acetic anhydride; trifluoroacetic acid; at 20 ℃; for 0.916667h;

With sodium; In methanol; at 20 ℃; for 2.66667h;
DOI:10.1016/j.carres.2010.03.002

Reference yield:

: 75348-19-5
1L-(1,2/2,4)-2,3,4-Tri-O-benzyl-5-C-(hydroxymethyl)-5-cyclohexen-1,2,3,4-tetrol

: 105017-72-9
1L-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-2,3,4,5-cyclohexantetrol

: 104976-78-5
1L-(1,3,5/2,4)-2,3,4-Tri-O-benzyl-5-C-hydroxymethyl-1,2,3,4-cyclohexantetrol

Guidance literature:: nickel; In 1,4-dioxane; for 4h; Yield given. Yields of byproduct given; Ambient temperature;

Reference yield:

: 104976-75-2
2D-(2,4/3)-2,3,4-Tri-O-benzyl-5-C-<(tert-butyldiphenylsilyloxy)methyl>-2,3,4-trihydroxy-5-cyclohexen-1-on

: 105017-72-9
1L-(1,2,4/3,5)-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-2,3,4,5-cyclohexantetrol

Guidance literature:: Multi-step reaction with 5 steps

1: 52 percent / NaBH₄ / ethanol / 12 h / Ambient temperature

2: 95 percent / Py / 12 h

3: 70 percent / Bu₄NF*3H₂O / tetrahydrofuran / 1 h / Ambient temperature

4: 81 percent / NaOMe (1M sol.) / methanol / 18 h / Ambient temperature

5: H₂ / Raney Ni / dioxane / 4 h / Ambient temperature

With pyridine; sodium tetrahydroborate; tetrabutyl ammonium fluoride; hydrogen; sodium methylate; nickel; In tetrahydrofuran; 1,4-dioxane; methanol; ethanol;