(1R,3R)-1,3-Diphenyl-N,N'-bis-[1-phenyl-meth-(E)-ylidene]-propane-1,3-diamine

Base Information

Chemical Name:(1R,3R)-1,3-Diphenyl-N,N'-bis-[1-phenyl-meth-(E)-ylidene]-propane-1,3-diamine
CAS No.:135614-40-3
Molecular Formula:C₂₉H₂₆N₂
Molecular Weight:402.539
Hs Code.:

Synonyms:(1R,3R)-1,3-Diphenyl-N,N'-bis-[1-phenyl-meth-(E)-ylidene]-propane-1,3-diamine

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Chemical Property of (1R,3R)-1,3-Diphenyl-N,N'-bis-[1-phenyl-meth-(E)-ylidene]-propane-1,3-diamine

Chemical Property:

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Technology Process of (1R,3R)-1,3-Diphenyl-N,N'-bis-[1-phenyl-meth-(E)-ylidene]-propane-1,3-diamine

There total 9 articles about (1R,3R)-1,3-Diphenyl-N,N'-bis-[1-phenyl-meth-(E)-ylidene]-propane-1,3-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 100-52-7
benzaldehyde

: 19293-52-8,59132-37-5,59158-71-3,59169-20-9,64364-63-2
racemic 1,3-diphenyl-1,3-propanediamine

: 135614-40-3
(1R,3R)-1,3-Diphenyl-N,N'-bis-[1-phenyl-meth-(E)-ylidene]-propane-1,3-diamine

Guidance literature:: In methanol;
DOI:10.1021/jo00017a016

Reference yield:

: 14371-10-9
(E)-3-phenylpropenal

: 135614-40-3
(1R,3R)-1,3-Diphenyl-N,N'-bis-[1-phenyl-meth-(E)-ylidene]-propane-1,3-diamine

Guidance literature:: Multi-step reaction with 6 steps

1: 66 percent / H₂NNH₂*H₂O / ethanol / 3 h / Heating

2: 89 percent / tetrahydrofuran / 12 h / Ambient temperature

3: 27 percent / PhLi / diethyl ether; tetrahydrofuran; cyclohexane / 2 h / -78 °C

4: 50percent TFA / CH₂Cl₂ / 2 h / Ambient temperature

5: H₂ / Raney-Ni / acetic acid; CH₂Cl₂ / 72 h / 31160 Torr

6: methanol / 1 h / Heating

With hydrogen; hydrazine hydrate; phenyllithium; trifluoroacetic acid; nickel; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; cyclohexane; acetic acid;
DOI:10.1055/s-1992-34183

Reference yield:

: 936-47-0
5-phenyl-4,5-dihydro-1H-pyrazole

: 135614-40-3
(1R,3R)-1,3-Diphenyl-N,N'-bis-[1-phenyl-meth-(E)-ylidene]-propane-1,3-diamine

Guidance literature:: Multi-step reaction with 5 steps

1: 89 percent / tetrahydrofuran / 12 h / Ambient temperature

2: 27 percent / PhLi / diethyl ether; tetrahydrofuran; cyclohexane / 2 h / -78 °C

3: 50percent TFA / CH₂Cl₂ / 2 h / Ambient temperature

4: H₂ / Raney-Ni / acetic acid; CH₂Cl₂ / 72 h / 31160 Torr

5: methanol / 1 h / Heating

With hydrogen; phenyllithium; trifluoroacetic acid; nickel; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; cyclohexane; acetic acid;
DOI:10.1055/s-1992-34183