L-aculose

Base Information

Chemical Name:L-aculose
CAS No.:247244-65-1
Molecular Formula:C₆H₈O₃
Molecular Weight:128.128
Hs Code.:

Synonyms:L-aculose

Suppliers and Price of L-aculose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of L-aculose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of L-aculose

There total 2 articles about L-aculose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 4208-64-4
1-(2-furyl)ethanol

: 247244-65-1
L-aculose

: 4208-64-4,27948-61-4,106565-48-4,112653-32-4
(S)-1-(2-furanyl)ethanol

: 27948-61-4
(R)-(+)-1-(2-furyl)ethanol

Guidance literature:: With titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; Yield given. Multistep reaction. Yields of byproduct given; 1a) CH₂Cl₂, molecular sieves 3 Angstroem, 1b) cooled, 30 min, 2) 5 h, -20 deg C, 2,2,4-trimethylpentane;

Reference yield:

: 78164-00-8
vineomycin A₁

: 51013-33-3
(4S,5S)-4,5-dihydroxy-hexanal (R)-1->5-cyclohemiacetal

: 247244-65-1
L-aculose

: 26055-63-0
aquayayamycin

Guidance literature:: With sulfuric acid; at 80 ℃; for 1h;
DOI:10.1248/cpb.32.4350

Reference yield:

: 247244-65-1
L-aculose

: 508-93-0
digitoxigenin 3-(α-L-rhamnopyranoside)

Guidance literature:: Multi-step reaction with 4 steps

1: dmap / dichloromethane / 12 h / -78 - -30 °C / Inert atmosphere

2: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; triphenylphosphine / tetrahydrofuran; dichloromethane / 6 h / 0 °C / Inert atmosphere

3: sodium tetrahydroborate; cerium(III) chloride / methanol; dichloromethane / 1 h / -78 °C

4: osmium(VIII) oxide; 4-methylmorpholine N-oxide / water; acetone; tert-butyl alcohol / 4 h / 0 °C

With dmap; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; sodium tetrahydroborate; osmium(VIII) oxide; cerium(III) chloride; 4-methylmorpholine N-oxide; triphenylphosphine; In tetrahydrofuran; methanol; dichloromethane; water; acetone; tert-butyl alcohol; 3: Luche reduction / 4: Upjohn dihydroxylation;
DOI:10.1021/ml100219d