(Xantphos)(4-cyanophenyl)bromopalladium(II)

Base Information

Chemical Name:(Xantphos)(4-cyanophenyl)bromopalladium(II)
CAS No.:335232-85-4
Molecular Formula:C₄₆H₃₆BrNOP₂Pd
Molecular Weight:867.069
Hs Code.:

Synonyms:(Xantphos)(4-cyanophenyl)bromopalladium(II)

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Chemical Property of (Xantphos)(4-cyanophenyl)bromopalladium(II)

Chemical Property:

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Technology Process of (Xantphos)(4-cyanophenyl)bromopalladium(II)

There total 2 articles about (Xantphos)(4-cyanophenyl)bromopalladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: tris(dibenzylideneacetone)dipalladium ⁽⁰⁾

: 623-00-7
4-bromobenzenecarbonitrile

: 161265-03-8
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene

: 335232-85-4
(Xantphos)(4-cyanophenyl)bromopalladium(II)

Guidance literature:: In benzene; soln. of Xantphos, Pd complex and BrC6H4CN (molar ratio 1.1:1:4.6) in benzene stirred at room temp. for 22 h; filtered through Celite; concd. in vac.; ether added; crystd. over 1 h; filtered; washed with ether; dried under vac.; elem. anal.;
DOI:10.1021/ja012610k

Reference yield: 57.0%

: 193001-39-7
[Pd[P(o-tolyl)3](p-benzonitrile)(μ-Br)]2

: 161265-03-8
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene

: 335232-85-4
(Xantphos)(4-cyanophenyl)bromopalladium(II)

Guidance literature:: In dichloromethane; Pd complex treated with ligand in CH2Cl2 at room temp. for 24 h;
DOI:10.1021/ja012610k

Reference yield:

: 335232-85-4
(Xantphos)(4-cyanophenyl)bromopalladium(II)

: 335232-85-4
cis-(Xantphos)(4-cyanophenyl)bromopalladium(II)

: 2923-28-6
silver trifluoromethanesulfonate

: 335232-92-3
(Xantphos)(4-cyanophenyl)palladium(II) triflate

Guidance literature:: In dichloromethane; acetonitrile; byproducts: AgBr; soln. of Pd complex (mixt. of cis- and trans-isomers) and AgOSO2CF3 (molar ratio 1:1) in CH2Cl2-MeCN stirred in the dark for 1 h; suspn. of Norit in CH2Cl2 added; stirred for 1 h; filtered; filtrate concd. under vac.; Et2O added; filtered; dried in vac.;
DOI:10.1039/b111596k