1-allyl-2-triisopropylsilyl(oxy)-3-amino-3,4-dihydro naphthalene

Base Information

Chemical Name:1-allyl-2-triisopropylsilyl(oxy)-3-amino-3,4-dihydro naphthalene
CAS No.:131515-97-4
Molecular Formula:C₃₁H₄₄BrNO₃SSi
Molecular Weight:618.751
Hs Code.:

1-allyl-2-triisopropylsilyl(oxy)-3-<N,N'-(4-methylphenylsulfonyl)-(2-bromoethyl)>amino-3,4-dihydro naphthalene

Synonyms:1-allyl-2-triisopropylsilyl(oxy)-3-amino-3,4-dihydro naphthalene

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Chemical Property of 1-allyl-2-triisopropylsilyl(oxy)-3-amino-3,4-dihydro naphthalene

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Technology Process of 1-allyl-2-triisopropylsilyl(oxy)-3-amino-3,4-dihydro naphthalene

There total 3 articles about 1-allyl-2-triisopropylsilyl(oxy)-3-amino-3,4-dihydro naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 131515-96-3
1-allyl-2-triisopropylsilyl(oxy)-3-(4-methylphenylsulfonyl)amino-3,4-dihydro naphthalene

: 106-93-4
ethylene dibromide

: 131515-97-4
1-allyl-2-triisopropylsilyl(oxy)-3-amino-3,4-dihydro naphthalene

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 80 ℃;
DOI:10.1021/ja00002a044

Reference yield:

: 13154-24-0
triisopropylsilyl chloride

: 131515-97-4
1-allyl-2-triisopropylsilyl(oxy)-3-amino-3,4-dihydro naphthalene

Guidance literature:: Multi-step reaction with 3 steps

1: 97 percent / potassium hexamethyldisilazide / tetrahydrofuran / 1 h / 0 °C

2: 59 percent / 1.) selenium / CH₂Cl₂ / Ambient temperature; 1.) 6 d; 2.) 2 h

3: 87 percent / sodium hydride / tetrahydrofuran / 1.) r.t., 1 h; 2.) reflux, 20 h

With selenium; potassium hexamethylsilazane; sodium hydride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0040-4020(95)00696-6

Reference yield:

: 131515-95-2
1-allyl-2-triisopropylsilyl(oxy)-3,4-dihydronaphthalene

: 131515-97-4
1-allyl-2-triisopropylsilyl(oxy)-3-amino-3,4-dihydro naphthalene

Guidance literature:: Multi-step reaction with 2 steps

1: 59 percent / 1.) selenium / CH₂Cl₂ / Ambient temperature; 1.) 6 d; 2.) 2 h

2: 87 percent / sodium hydride / tetrahydrofuran / 1.) r.t., 1 h; 2.) reflux, 20 h

With selenium; sodium hydride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0040-4020(95)00696-6