[(H)Ru(CO)(bis(diphenylphosphino)ethylene)-(5-amino-1,10-phenanthroline)] hexafluorophosphate

Base Information

• Chemical Name: [(H)Ru(CO)(bis(diphenylphosphino)ethylene)-(5-amino-1,10-phenanthroline)] hexafluorophosphate
• CAS No.: 1147124-97-7
• Molecular Formula: C₃₉H₃₂N₃OP₂Ru*F₆P
• Molecular Weight: 866.684

Synonyms:[(H)Ru(CO)(bis(diphenylphosphino)ethylene)-(5-amino-1,10-phenanthroline)] hexafluorophosphate

Chemical Property of [(H)Ru(CO)(bis(diphenylphosphino)ethylene)-(5-amino-1,10-phenanthroline)] hexafluorophosphate

Chemical Property:

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Technology Process of [(H)Ru(CO)(bis(diphenylphosphino)ethylene)-(5-amino-1,10-phenanthroline)] hexafluorophosphate

There total 2 articles about [(H)Ru(CO)(bis(diphenylphosphino)ethylene)-(5-amino-1,10-phenanthroline)] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 1.0%

[Ru(η2-Ph2PC2H2PPh2)(trifluoroacetate)(CO)(5-amino-1,10-phenanthroline)]PF6 (1147124-95-5) + sodium chloride (7647-14-5) → [(H)Ru(CO)(bis(diphenylphosphino)ethylene)-(5-amino-1,10-phenanthroline)] hexafluorophosphate (1147124-97-7) + [ClRu(η2-Ph2PC2H2PPh2)(CO)(5-amino-1,10-phenanthroline)]PF6 (1147124-99-9)

Guidance literature:

In methanol; water; (N2); aq. NaCl was added to soln. of Ru complex in MeOH;

DOI:10.1016/j.jorganchem.2008.11.048

Reference yield: 1.0%

hydrogenchloride (7647-01-0,15364-23-5) + [Ru(η2-Ph2PC2H2PPh2)(trifluoroacetate)(CO)(5-amino-1,10-phenanthroline)]PF6 (1147124-95-5) → [(H)Ru(CO)(bis(diphenylphosphino)ethylene)-(5-amino-1,10-phenanthroline)] hexafluorophosphate (1147124-97-7) + [ClRu(η2-Ph2PC2H2PPh2)(CO)(5-amino-1,10-phenanthroline)]PF6 (1147124-99-9)

Guidance literature:

In methanol; (N2); concd. HCl was added to soln. of Ru complex in MeOH;

DOI:10.1016/j.jorganchem.2008.11.048

Reference yield: 94.0%

[(H)Ru(CO)(bis(diphenylphosphino)ethylene)-(5-amino-1,10-phenanthroline)] hexafluorophosphate (1147124-97-7) → [(H)Ru(CO)(bis(diphenylphosphino)ethylene)-(1,10-phenanthroline-5-NCS)] hexafluorophosphate

Guidance literature:

With thiophosgene; calcium carbonate; In acetone; at 20 ℃; for 3.5h; Inert atmosphere; Reflux;

DOI:10.1021/ic400706u

upstream raw materials:

[Ru(η2-Ph2PC2H2PPh2)(trifluoroacetate)(CO)(5-amino-1,10-phenanthroline)]PF6

sodium chloride

hydrogenchloride

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