(2S,6S)-1-(benzyloxy)-2,6-dimethyldec-9-en-5-one

Base Information

Chemical Name:(2S,6S)-1-(benzyloxy)-2,6-dimethyldec-9-en-5-one
CAS No.:1408299-05-7
Molecular Formula:C₁₉H₂₈O₂
Molecular Weight:288.43
Hs Code.:

Synonyms:(2S,6S)-1-(benzyloxy)-2,6-dimethyldec-9-en-5-one

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Chemical Property of (2S,6S)-1-(benzyloxy)-2,6-dimethyldec-9-en-5-one

Chemical Property:

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Technology Process of (2S,6S)-1-(benzyloxy)-2,6-dimethyldec-9-en-5-one

There total 8 articles about (2S,6S)-1-(benzyloxy)-2,6-dimethyldec-9-en-5-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 1408299-04-6
(2S,5R,6S)-1-(benzyloxy)-2,6-dimethyldec-9-en-5-ol

: 1408299-05-7
(2S,6S)-1-(benzyloxy)-2,6-dimethyldec-9-en-5-one

Guidance literature:: With 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In dimethyl sulfoxide; at 20 ℃; for 2h;
DOI:10.1016/j.tetasy.2012.07.006

Reference yield:

: 887706-39-0
(S)-5-(benzyloxy)-4-methylpentan-1-ol

: 1408299-05-7
(2S,6S)-1-(benzyloxy)-2,6-dimethyldec-9-en-5-one

Guidance literature:: Multi-step reaction with 6 steps

1.1: Dess-Martin periodane / dichloromethane / 1 h / 20 °C

2.1: di-n-butylboryl trifluoromethanesulfonate / dichloromethane / 0.17 h / 0 °C

2.2: 0.5 h / 0 °C

2.3: 1 h / 0 °C

3.1: sodium tetrahydroborate / tetrahydrofuran; water / 20 °C

4.1: dmap; triethylamine / dichloromethane / 20 h / 0 - 20 °C

5.1: lithium aluminium tetrahydride / tetrahydrofuran / 3 h / Reflux

6.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 2 h / 20 °C

With dmap; sodium tetrahydroborate; lithium aluminium tetrahydride; di-n-butylboryl trifluoromethanesulfonate; Dess-Martin periodane; triethylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; dichloromethane; water; dimethyl sulfoxide; 2.1: |Evans Aldol Reaction / 2.2: |Evans Aldol Reaction;
DOI:10.1016/j.tetasy.2012.07.006

Reference yield:

: 134916-00-0
(4S)-4-benzyl-3-(hex-5-enoyl)-1,3-oxazolidin-2-one

: 1408299-05-7
(2S,6S)-1-(benzyloxy)-2,6-dimethyldec-9-en-5-one

Guidance literature:: Multi-step reaction with 5 steps

1.1: di-n-butylboryl trifluoromethanesulfonate / dichloromethane / 0.17 h / 0 °C

1.2: 0.5 h / 0 °C

1.3: 1 h / 0 °C

2.1: sodium tetrahydroborate / tetrahydrofuran; water / 20 °C

3.1: dmap; triethylamine / dichloromethane / 20 h / 0 - 20 °C

4.1: lithium aluminium tetrahydride / tetrahydrofuran / 3 h / Reflux

5.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 2 h / 20 °C

With dmap; sodium tetrahydroborate; lithium aluminium tetrahydride; di-n-butylboryl trifluoromethanesulfonate; triethylamine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; dichloromethane; water; dimethyl sulfoxide; 1.1: |Evans Aldol Reaction / 1.2: |Evans Aldol Reaction;
DOI:10.1016/j.tetasy.2012.07.006