tetraphenylporphyrine (dichlo)roplatinum(IV)

Base Information

• Chemical Name: tetraphenylporphyrine (dichlo)roplatinum(IV)
• CAS No.: 154861-29-7
• Molecular Formula: C₄₄H₂₈Cl₂N₄Pt
• Molecular Weight: 878.719
• Mol file: 154861-29-7.mol

Synonyms:tetraphenylporphyrine (dichlo)roplatinum(IV)

Chemical Property of tetraphenylporphyrine (dichlo)roplatinum(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraphenylporphyrine (dichlo)roplatinum(IV)

There total 5 articles about tetraphenylporphyrine (dichlo)roplatinum(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

platinum(II) 5,10,15,20-tetraphenylporphyrinate (14187-14-5) → tetraphenylporphyrine (dichlo)roplatinum(IV) (154861-29-7)

Guidance literature:

With hydrogenchloride; dihydrogen peroxide; In chloroform; refluxed; 30 min;; cooled; washed with water; organic layer dried over MgSO4; filtered; chromd. (SiO2, CH2Cl2, then CHCl3); recrystd. from CHCl3/MeOH;;

DOI:10.1016/S0277-5387(00)86593-6

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + platinum(II) 5,10,15,20-tetraphenylporphyrinate (14187-14-5) → tetraphenylporphyrine (dichlo)roplatinum(IV) (154861-29-7)

Guidance literature:

With dihydrogen peroxide; In chloroform; refluxing (2 h); washing (H2O), solvent removal, dissolving (toluene), chromatography, solvent redn., pptn. on MeOH addn., filtn., washing (MeOH, H2O);

DOI:10.1016/S0277-5387(97)00026-0

Reference yield:

5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → tetraphenylporphyrine (dichlo)roplatinum(IV) (154861-29-7)

Guidance literature:

Multi-step reaction with 2 steps

1: benzonitrile / 12 h / 210 °C

2: dihydrogen peroxide / chloroform; water / 0.5 h / 100 °C

With dihydrogen peroxide; In chloroform; water; benzonitrile;

DOI:10.1016/j.tetlet.2013.08.128

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

hydrogenchloride

platinum(II) 5,10,15,20-tetraphenylporphyrinate

chlorine