1‐phenyl‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolium tetrafluoroborate

Base Information

• Chemical Name: 1‐phenyl‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolium tetrafluoroborate
• CAS No.: 1434057-41-6
• Molecular Formula: BF₄*C₁₈H₁₉N₂
• Molecular Weight: 350.167
• Mol file: 1434057-41-6.mol

Synonyms:1‐phenyl‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolium tetrafluoroborate

Chemical Property of 1‐phenyl‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolium tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1‐phenyl‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolium tetrafluoroborate

There total 2 articles about 1‐phenyl‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolium tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

diphenyliodonium tetrafluoroborate + N-(2,4,6-trimethylphenyl)imidazole (25364-44-7) → 1‐phenyl‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolium tetrafluoroborate (1434057-41-6)

Guidance literature:

With copper(II) acetate monohydrate; In N,N-dimethyl-formamide; at 100 ℃; for 12h; Schlenk technique;

DOI:10.1021/jo400527r

Reference yield: 66.0%

N-(2,4,6-trimethylphenyl)imidazole (25364-44-7) + phenylboronic acid (98-80-6) → 1‐phenyl‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolium tetrafluoroborate (1434057-41-6)

Guidance literature:

With iron(III) chloride; tetrafluoroboric acid; ammonium tetrafluroborate; copper(II) acetate monohydrate; In water; N,N-dimethyl-formamide; at 100 ℃; for 10h; chemoselective reaction; Schlenk technique;

DOI:10.1039/c4cc00474d

Reference yield: 58.0%

dichloro( 1,5-cyclooctadiene)platinum(ll) (12080-32-9) + 1‐phenyl‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolium tetrafluoroborate (1434057-41-6) + acetylacetone (123-54-6,81235-32-7) → [acetylacetonato‐κO,κO'][1‐(phenyl‐κC2)‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolin‐2‐ylidene‐κC2]platinum(II)

Guidance literature:

1‐phenyl‐3‐(2,4,6‐trimethylphenyl)‐1H‐imidazolium tetrafluoroborate; With silver(l) oxide; In N,N-dimethyl-formamide; at 45 ℃; for 24h; Schlenk technique; Inert atmosphere;

dichloro( 1,5-cyclooctadiene)platinum(ll); In N,N-dimethyl-formamide; at 20 - 115 ℃; for 24h; Schlenk technique; Inert atmosphere;

acetylacetone; With potassium carbonate; In N,N-dimethyl-formamide; at 20 - 100 ℃; for 27h; Schlenk technique; Inert atmosphere;

DOI:10.1002/anie.202011927

upstream raw materials:

N-(2,4,6-trimethylphenyl)imidazole

phenylboronic acid