closo-tetraphosphorushexabenzylimide

Base Information

• Chemical Name: closo-tetraphosphorushexabenzylimide
• CAS No.: 1262954-73-3
• Molecular Formula: C₄₂H₄₂N₆P₄
• Molecular Weight: 754.731
• Mol file: 1262954-73-3.mol

Synonyms:closo-tetraphosphorushexabenzylimide

Chemical Property of closo-tetraphosphorushexabenzylimide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of closo-tetraphosphorushexabenzylimide

There total 1 articles about closo-tetraphosphorushexabenzylimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

benzylamine (100-46-9) → closo-tetraphosphorushexabenzylimide (1262954-73-3)

Guidance literature:

benzylamine; With n-butyllithium; In tetrahydrofuran; at 0 - 20 ℃; for 1h; Inert atmosphere;

With phosphorus trichloride; In tetrahydrofuran; at -60 - 20 ℃; for 19h; Inert atmosphere;

With triethylamine; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.ica.2010.08.052

Reference yield: 30.0%

copper(l) iodide (7681-65-4) + closo-tetraphosphorushexabenzylimide (1262954-73-3) + acetonitrile (75-05-8,26809-02-9) → [(copper(I)iodide)2(tetraphosphorushexabenzylimide)(acetonitrile)2] acetonitrile monosolvate

Guidance literature:

In acetonitrile; Schlenk or glove box techniques, under N2; CuI (0.662 mmol) soln. added to soln. of P4(NEt)6 (0.598 mmol), stirred; crystd. (3 d), supernatant removed, ppt. washed with MeCN, elem. anal.;

DOI:10.1016/j.ica.2010.08.052

upstream raw materials:

benzylamine