Marshite

Base Information

• Chemical Name: Marshite
• CAS No.: 7681-65-4
• Deprecated CAS: 265669-02-1,40452-11-7
• Molecular Formula: CuI
• Molecular Weight: 190.451
• Hs Code.: HYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE white to gray-beige powder
• UNII: 7DE9CA6IL2
• DSSTox Substance ID: DTXSID5041803
• Nikkaji Number: J95.202H
• Wikipedia: Marshite
• Mol file: 7681-65-4.mol

Synonyms:Copper(l)iodide;Marshite;DTXSID5041803;CUPROUS IODIDE [MI];CUPROUS IODIDE [INCI];DTXCID3021803;COPPER(I) IODIDE [HSDB];Tox21_300719;AKOS022183837;NCGC00254625-01;CAS-7681-65-4;C2163;Copper(I) iodide (99.999%-Cu) PURATREM;D78015;J-520123

Chemical Property of Marshite

Chemical Property:

• Appearance/Colour: white to grey or tan powder
• Melting Point: 605 °C(lit.)
• Refractive Index: 2.346
• Boiling Point: 1290 °C
• Flash Point: 1290°C
• PSA: 0.00000
• Density: 5.62 g/cm³
• LogP: -2.99850
• Water Solubility.: INSOLUBLE
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 189.83407
• Heavy Atom Count: 2
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xn,N,Xi
• Hazard Codes: Xi:Irritant
• Statements: R36/37/38:
• Safety Statements: S24/25:

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cu+].[I-]

Technology Process of Marshite

There total 173 articles about Marshite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

copper(II) oxotriiodoantimonate(III) → antimony(III) trioxide + copper(l) iodide (7681-65-4) + hydrogen iodide (10034-85-2)

Guidance literature:

In water;

Reference yield:

iodine (7553-56-2,12190-71-5,8031-47-8) + copper(ll) bromide (7789-45-9) → copper(l) iodide (7681-65-4) + copper(I) bromide (7787-70-4)

Guidance literature:

In ethanol; reaction of alcoholic soln. of iodine with CuBr2 at 60°C; X-ray diffraction; Kinetics;

Reference yield:

(C3H7)4N(1+)*CuI3(1-)={(C3H7)4N}CuI3 → copper(l) iodide (7681-65-4) + tetrapropylammonium iodide (631-40-3) + iodine (7553-56-2,12190-71-5,8031-47-8)

Guidance literature:

In water;

DOI:10.1039/CT9130300426

upstream raw materials:

iodine

copper

potassium iodide

copper(I) bromide

Downstream raw materials:

N-(3-iodophenyl)morpholine

2,2-dimethyl-5-{3-[(5-methyl-2-phenyloxazol-4-yl)methyl]benzyl}-1,3-dioxane

(R)-N-(1-Azabicyclo[2.2.2]oct-3-yl)(5-phenoxythiophene-2-carboxamide)

1-(pyridin-3-yl)-1-propyn-3-ol

Refernces

• 1、 Hannay, J. B.. "". . p. 815 - 823. Retrieved 1873.
• 2、 Lobana, Tarlok S.,Sultana, Razia,Butcher, Ray J.,Castineiras, Alfonso,Akitsu, Takashiro,Fernandez, Francisco J.,Vega, M. Cristina. "Chemistry of heterocyclic 2-thiones: In situ generation of 3-(2-thiazolin-2-yl)thiazolidine-2-thione and 1,1′-dimethyl-2,2′- diimidazolyl sulfide and their coordination to CuI and Cu II". . p. 5161 - 5170. Retrieved 2013.
• 3、 Schmidt, Jorge A.,Batan, Julio C.. "". . p. 227 - 230. Retrieved 1986.
• 4、 McGuire, Michael A.,Ranjan, Chinmoy,DiSalvo, Francis J.. "Cu4Mo6Se8: Synthesis, crystal structure, and electronic structure of a new Chevrel phase structure type". . p. 2718 - 2726. Retrieved 2006.
• 5、 James,Goodenough,Clayden,Banks. "Characterization of defect thiospinels Cu1-x[Ti2 ]S4 (0 . p. 143 - 155. Retrieved 1989.
• 6、 Hwang, Jae-Yeol,Mun, Hyeon A.,Kim, Sang Il,Lee, Ki Moon,Kim, Jungeun,Lee, Kyu Hyoung,Kim, Sung Wng. "Effects of doping on transport properties in Cu-Bi-Se-based thermoelectric materials". . p. 12732 - 12738. Retrieved 2014.
• 7、 Harrison, W. D.,Gill, J. B.,Goodall, D. C.. "". . p. 153 - 156. Retrieved 1983.
• 8、 Kwiatkowski, Edmund,Ossowski, Tadeusz,Jankowska, Anna. "". . p. 1191 - 1196. Retrieved 1985.
• 9、 Geller, S.,Akridge, J. R.,Wolber, S. A.. "". . . Retrieved 1979.
• 10、 Razi, Fariba,Soofivand, Faezeh,Salavati-Niasari, Masoud. "Cu2ZnI4/ZnO nanocomposites: In-situ synthesis, characterization and optical properties". . p. 435 - 440. Retrieved 2016.