4a-hydroperoxy-N⁵-ethyl-N³-methyllumiflavin

Base Information

• Chemical Name: 4a-hydroperoxy-N⁵-ethyl-N³-methyllumiflavin
• CAS No.: 59587-26-7
• Molecular Formula: C₁₆H₂₀N₄O₄
• Molecular Weight: 332.359
• Mol file: 59587-26-7.mol

Synonyms:4a-hydroperoxy-N⁵-ethyl-N³-methyllumiflavin

Chemical Property of 4a-hydroperoxy-N⁵-ethyl-N³-methyllumiflavin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4a-hydroperoxy-N⁵-ethyl-N³-methyllumiflavin

There total 1 articles about 4a-hydroperoxy-N⁵-ethyl-N³-methyllumiflavin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

5-ethyl-4a-hydroxy-3-methyl-4a,5-dihydrolumiflavin pseudobase (50387-45-6) → 4a-hydroperoxy-N5-ethyl-N3-methyllumiflavin (59587-26-7)

Guidance literature:

With dihydrogen peroxide; In methanol; Ambient temperature;

DOI:10.1021/ja00195a076

Reference yield: 80.0%

2-amino-phenol (95-55-6) + 4a-hydroperoxy-N5-ethyl-N3-methyllumiflavin (59587-26-7) → 2-aminophenoxazin-3-one (1916-59-2)

Guidance literature:

With potassium tert-butylate; In tert-butyl alcohol; at 30 ℃; Product distribution; Rate constant; Mechanism; var. aminophenols and aminonaphthols;

DOI:10.1021/ja00163a037

Reference yield: 57.0%

5-methoxy-3-methyl-2-phenyl-1H-indole (64648-65-3) + 4a-hydroperoxy-N5-ethyl-N3-methyllumiflavin (59587-26-7) → 1,5-dihydro-N5-ethyl-3-methyllumiflavin (50387-36-5) + 3-(hydroperoxy)-5-methoxy-3-methyl-2-phenylindolenine (75702-65-7) + 2-benzamido-5-methoxyacetophenone + 3-hydroxy-5-methoxy-3-methyl-2-phenylindolenine (75702-64-6)

Guidance literature:

With potassium tert-butylate; In tert-butyl alcohol; at 30 ℃; for 0.166667h; Rate constant; Mechanism;

DOI:10.1021/ja00545a028

upstream raw materials:

5-ethyl-4^a-hydroxy-3-methyl-4^a,5-dihydrolumiflavin pseudobase

Downstream raw materials:

1,5-dihydro-N⁵-ethyl-3-methyllumiflavin

3-hydroxy-2,3-dimethylindolenine

2,3-dimethyl-3-(hydroperoxy)indolenine

N-(2-acetylphenyl)acetamide