C₄₄H₆₀O₇Si

Base Information

Chemical Name:C₄₄H₆₀O₇Si
CAS No.:532393-22-9
Molecular Formula:C₄₄H₆₀O₇Si
Molecular Weight:729.042
Hs Code.:

C<sub>44</sub>H<sub>60</sub>O<sub>7</sub>Si

Synonyms:C₄₄H₆₀O₇Si

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Chemical Property of C₄₄H₆₀O₇Si

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Technology Process of C₄₄H₆₀O₇Si

There total 9 articles about C₄₄H₆₀O₇Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 204199-71-3,92081-13-5,130860-32-1
trans-1-(tri-n-butylstannyl)hept-1-ene

: 532393-14-9
C₃₇H₄₇BrO₇Si

: 532393-22-9
C₄₄H₆₀O₇Si

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; at 110 ℃; for 3h;
DOI:10.1021/ja021396c

Reference yield:

: 347840-66-8
[[2-bromo-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-6-methoxyphenyl]methoxy](1,1-dimethylethyl)diphenylsilane

: 532393-22-9
C₄₄H₆₀O₇Si

Guidance literature:: Multi-step reaction with 9 steps

1.1: TBAF / tetrahydrofuran / 0.17 h / 0 °C

2.1: K₂CO₃ / dimethylformamide / 2.5 h / 20 °C

3.1: 2 h / 180 °C

3.2: 70 percent / PhI(OAc)2 / 0.33 h / 20 °C

4.1: 82 percent / pyridinium p-toluenesulfonate / benzene / 0.5 h / 80 °C

5.1: 73 percent / Ph₃COOH; KHMDS / tetrahydrofuran; toluene / 25 h / -35 °C

6.1: N-methylmorpholine oxide; OsO₄ / tetrahydrofuran; H₂O; toluene / 20 h / 20 °C

7.1: Pb(OAc)4 / tetrahydrofuran / 0.08 h / 20 °C

8.1: 43 mg / CH₂Cl₂ / 2 h / -78 - -5 °C

9.1: 94 percent / Pd(PPh₃)4 / toluene / 3 h / 110 °C

With lead(IV) acetate; osmium(VIII) oxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; trityl hydroperoxide; tetrabutyl ammonium fluoride; pyridinium p-toluenesulfonate; potassium hexamethylsilazane; potassium carbonate; 4-methylmorpholine N-oxide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; toluene; benzene; 3.1: Claisen rearrangement;
DOI:10.1021/ja021396c

Reference yield:

: 347840-54-4
2-bromo-3-[[[(1,1-dimethylethyl)diphenylsilyl]oxy]methyl]-4-methoxyphenol

: 532393-22-9
C₄₄H₆₀O₇Si

Guidance literature:: Multi-step reaction with 8 steps

1.1: K₂CO₃ / dimethylformamide / 2.5 h / 20 °C

2.1: 2 h / 180 °C

2.2: 70 percent / PhI(OAc)2 / 0.33 h / 20 °C

3.1: 82 percent / pyridinium p-toluenesulfonate / benzene / 0.5 h / 80 °C

4.1: 73 percent / Ph₃COOH; KHMDS / tetrahydrofuran; toluene / 25 h / -35 °C

5.1: N-methylmorpholine oxide; OsO₄ / tetrahydrofuran; H₂O; toluene / 20 h / 20 °C

6.1: Pb(OAc)4 / tetrahydrofuran / 0.08 h / 20 °C

7.1: 43 mg / CH₂Cl₂ / 2 h / -78 - -5 °C

8.1: 94 percent / Pd(PPh₃)4 / toluene / 3 h / 110 °C

With lead(IV) acetate; osmium(VIII) oxide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; trityl hydroperoxide; pyridinium p-toluenesulfonate; potassium hexamethylsilazane; potassium carbonate; 4-methylmorpholine N-oxide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; toluene; benzene; 2.1: Claisen rearrangement;
DOI:10.1021/ja021396c