Hexane-1,2,3,4,5-pentol

Base Information

• Chemical Name: Hexane-1,2,3,4,5-pentol
• CAS No.: 5328-43-8
• Molecular Formula: C17H27NO3S
• Molecular Weight: 166.174
• NSC Number: 1957,1948
• Wikidata: Q105254737
• Metabolomics Workbench ID: 75597
• Mol file: 5328-43-8.mol

Synonyms:hexane-1,2,3,4,5-pentol;NSC1948;FUCITOL (L);NSC-1957;1-Deoxyhexitol #;6-Deoxy-L-gulitol;6-Desoxy-l-altritol;6-DEOXY-D-DULCITOL;SCHEMBL136701;NSC1957;CHEBI:165503;SKCKOFZKJLZSFA-UHFFFAOYSA-N;BCP30265;NSC-1948;LMFA05000598;AKOS024319435;L-Fucitol pound>>6-Deoxy-L-galactitol;J-005870

Chemical Property of Hexane-1,2,3,4,5-pentol

Chemical Property:

• Vapor Pressure: 3.66E-10mmHg at 25°C
• Boiling Point: 468°Cat760mmHg
• Flash Point: 244.3°C
• Density: 1.424g/cm³
• XLogP3: -2
• Hydrogen Bond Donor Count: 5
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 166.08412354
• Heavy Atom Count: 11
• Complexity: 107

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C(C(C(CO)O)O)O)O

Technology Process of Hexane-1,2,3,4,5-pentol

There total 7 articles about Hexane-1,2,3,4,5-pentol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

D-Fucose (3615-37-0,478518-52-4) → 1-deoxy-L-galactitol (5328-43-8)

Guidance literature:

With hydrogen; nickel; In water; at 50 ℃; for 24h; under 9000.9 Torr;

DOI:10.1016/j.tetasy.2008.02.013

Reference yield:

3(S)-Linalool β-D-(6'-O-β-L-Fucopyranosyl)glucopyranosid (84534-33-8,104154-34-9,131348-52-2,131348-59-9) → D-glucose (50-99-7) + (S)-(+)-linalool (126-90-9) + 1-deoxy-L-galactitol (5328-43-8)

Guidance literature:

With citrate buffer; at 40 ℃; for 5h; enzyme hesperidinase;

Reference yield:

→ rhodeitol and fucitol (488-28-8,1114-16-5,5328-43-8,5624-40-8,13074-06-1,18545-96-5,18545-98-7,33947-09-0,37114-30-0,51607-21-7,60965-81-3,68832-18-8,71075-63-3,73804-38-3,86334-50-1,88156-01-8,88156-34-7,95120-27-7,123672-37-7,134002-88-3,134002-91-8)

Guidance literature:

With sodium amalgam;

upstream raw materials:

D-Fucose

hexane-1,2,3,4,5-pentaol

L-fucitol

L-Fucose

Downstream raw materials:

racemic rhodeitol

6-deoxy-D-lyxo-2-hexulose

Refernces

• 1、 Yoshihara, Akihide,Haraguchi, Satoshi,Gullapalli, Pushpakiran,Rao, Davendar,Morimoto, Kenji,Takata, Goro,Jones, Nigel,Jenkinson, Sarah F.,Wormald, Mark R.,Dwek, Raymond A.,Fleet, George W.J.,Izumori, Ken. "Isomerization of deoxyhexoses: green bioproduction of 1-deoxy-d-tagatose from l-fucose and of 6-deoxy-d-tagatose from d-fucose using Enterobacter agglomerans strain 221e". . p. 739 - 745. Retrieved 2008/09/20.
• 2、 Haga, Hidehiko,Nakajima, Terumi. "Analysis of Aldoses and Alditols by Capillary Gas Chromatography as Alditol Trifluoroacetates". . p. 1562 - 1564. Retrieved 2007/10/02.