(+)-(R)-7-(benzyloxy)-3-methylheptanal

Base Information

• Chemical Name: (+)-(R)-7-(benzyloxy)-3-methylheptanal
• CAS No.: 1424403-34-8
• Molecular Formula: C₁₅H₂₂O₂
• Molecular Weight: 234.338
• Mol file: 1424403-34-8.mol

Synonyms:(+)-(R)-7-(benzyloxy)-3-methylheptanal

Chemical Property of (+)-(R)-7-(benzyloxy)-3-methylheptanal

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+)-(R)-7-(benzyloxy)-3-methylheptanal

There total 16 articles about (+)-(R)-7-(benzyloxy)-3-methylheptanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

(+)-S-ethyl (R)-7-(benzyloxy)-3-methylheptanethioate → (+)-(R)-7-(benzyloxy)-3-methylheptanal (1424403-34-8)

Guidance literature:

With diisobutylaluminium hydride; In dichloromethane; at -78 ℃; Inert atmosphere;

DOI:10.1039/c7cc05433e

Reference yield: 90.0%

(R)-methyl 7-(benzyloxy)-3-methylheptanoate (1424403-20-2) → (+)-(R)-7-(benzyloxy)-3-methylheptanal (1424403-34-8)

Guidance literature:

With diisobutylaluminium hydride; In toluene; at -78 ℃; for 0.166667h;

DOI:10.1016/j.tet.2013.01.048

Reference yield:

(R)-7-(benzyloxy)-3-methylheptanenitrile → (+)-(R)-7-(benzyloxy)-3-methylheptanal (1424403-34-8)

Guidance literature:

(R)-7-(benzyloxy)-3-methylheptanenitrile; With diisobutylaluminium hydride; In hexane; dichloromethane; at -78 ℃; for 1h; Inert atmosphere;

With methanol; In hexane; dichloromethane; at 20 ℃; for 0.5h; Inert atmosphere;

DOI:10.1002/ejoc.201600325

upstream raw materials:

6-benzyloxy-1-hexanal

6-benzyloxyhexanoic acid

6-benzyloxyhexan-1-ol

(R)-4-benzyl-3-((R)-6-(benzyloxy)-2-methylhexanoyl)oxazolidin-2-one

Downstream raw materials:

(5R,7R)-methyl 7-(((R)-6-(benzyloxy)-2-methylhexanoyl)oxy)-5,8,8-trimethylnonanoate

(R)-(3R,5R)-2,2,5-trimethyl-9-(methylamino)-9-oxononan-3-yl 6-(benzyloxy)-2-methylhexanoate

(5R,7R)-7-(((R)-6-(benzyloxy)-2-methylhexanoyl)oxy)-5,8,8-trimethylnonanoic acid

(5R)-9-(benzyloxy)-2,2,5-trimethylnonan-3-ol