tert-Butyl-dimethyl-(2-{2-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-[1,3]dithian-2-yl}-ethoxy)-silane

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Chemical Name:tert-Butyl-dimethyl-(2-{2-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-[1,3]dithian-2-yl}-ethoxy)-silane
CAS No.:121846-24-0
Molecular Formula:C₂₃H₄₂OS₂Si
Molecular Weight:426.803
Hs Code.:

Synonyms:tert-Butyl-dimethyl-(2-{2-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-[1,3]dithian-2-yl}-ethoxy)-silane

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Chemical Property of tert-Butyl-dimethyl-(2-{2-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-[1,3]dithian-2-yl}-ethoxy)-silane

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Technology Process of tert-Butyl-dimethyl-(2-{2-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-[1,3]dithian-2-yl}-ethoxy)-silane

There total 1 articles about tert-Butyl-dimethyl-(2-{2-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-[1,3]dithian-2-yl}-ethoxy)-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 101166-65-8
2-tert-butyldimethylsilyloxyethyl iodide

: 121846-23-9
(E)-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-propenal S,S-acetal

: 121846-24-0
tert-Butyl-dimethyl-(2-{2-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-[1,3]dithian-2-yl}-ethoxy)-silane

Guidance literature:: With n-butyllithium; In tetrahydrofuran; at -78 ℃;
DOI:10.1021/ja00195a073

Reference yield:

: 121846-24-0
tert-Butyl-dimethyl-(2-{2-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-[1,3]dithian-2-yl}-ethoxy)-silane

: 121846-34-2
C₂₉H₄₃O₇S^(1-)*K⁽¹⁺⁾

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) HgCl₂, HgO, 2.) Et₃N / 1.) 95percent aq. MeOH, reflux, 2.) CH₂Cl₂

2: 1.) NaH, 2.) DIBAL / 1.) THF, 2.) Et₂O, -78 deg C

4: 1.) DCC, DMAP, 2.) C₅H₅N, n-Bu₄NF / 1.) CH₂Cl₂, 2.) THF

5: SO₃*C₅H₅N, KCl / pyridine; H₂O

With pyridine; dmap; potassium chloride; tetrabutyl ammonium fluoride; sulfur trioxide pyridine complex; sodium hydride; diisobutylaluminium hydride; triethylamine; dicyclohexyl-carbodiimide; mercury dichloride; mercury(II) oxide; In pyridine; water;
DOI:10.1021/ja00195a073

Reference yield:

: 121846-24-0
tert-Butyl-dimethyl-(2-{2-[(E)-2-(2,6,6-trimethyl-cyclohex-1-enyl)-vinyl]-[1,3]dithian-2-yl}-ethoxy)-silane

: 121846-33-1
C₃₁H₄₇O₇S^(1-)*K⁽¹⁺⁾

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) HgCl₂, HgO, 2.) Et₃N / 1.) 95percent aq. MeOH, reflux, 2.) CH₂Cl₂

2: 1.) NaH, 2.) DIBAL / 1.) THF, 2.) Et₂O, -78 deg C

4: 1.) DCC, DMAP, 2.) n-Bu₄NF / 1.) CH₂Cl₂, 2.) THF

5: SO₃*C₅H₅N, KCl / pyridine; H₂O

With dmap; potassium chloride; tetrabutyl ammonium fluoride; sulfur trioxide pyridine complex; sodium hydride; diisobutylaluminium hydride; triethylamine; dicyclohexyl-carbodiimide; mercury dichloride; mercury(II) oxide; In pyridine; water;
DOI:10.1021/ja00195a073