((t-Bu₂PCH₂SiMe₂)2N)RuCl

Base Information

Chemical Name:((t-Bu₂PCH₂SiMe₂)2N)RuCl
CAS No.:574703-69-8
Molecular Formula:C₂₂H₅₂ClNP₂RuSi₂
Molecular Weight:585.303
Hs Code.:

((t-Bu<sub>2</sub>PCH<sub>2</sub>SiMe<sub>2</sub>)2N)RuCl

Synonyms:((t-Bu₂PCH₂SiMe₂)2N)RuCl

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Chemical Property of ((t-Bu₂PCH₂SiMe₂)2N)RuCl

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Technology Process of ((t-Bu₂PCH₂SiMe₂)2N)RuCl

There total 1 articles about ((t-Bu₂PCH₂SiMe₂)2N)RuCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1063758-31-5
[((t-Bu₂PCH₂SiMe₂)2N)Ru(NPh)][((t-Bu₂PCH₂SiMe₂)2N)RuCl₃]

: 574703-69-8
((t-Bu₂PCH₂SiMe₂)2N)RuCl

: 1063758-32-6
((t-Bu₂PCH₂SiMe₂)2N)Ru(NPh)

Guidance literature:: With zinc; In tetrahydrofuran-d8; under Ar atm. to soln. Ru complex in THF-d8 was added excess Zn and stirred overnight; NMR spectroscopy;
DOI:10.1021/ic801035z

Reference yield:

: 1693-74-9
tetrahydrofuran-d8

: 574703-69-8
((t-Bu₂PCH₂SiMe₂)2N)RuCl

: 7727-37-9
nitrogen

: Ru⁽²⁺⁾*H^(1-)*N(Si(CH₃)2CH₂P(C(CH₃)3)2)2^(1-)*N₂=RuH(N(Si(CH₃)2CH₂P(C(CH₃)3)2)2)(N₂)

: Ru⁽²⁺⁾*⁽²⁾H^(1-)*N(Si(CH₃)2CH₂P(C(CH₃)3)2)2^(1-)*N₂=Ru⁽²⁾H(N(Si(CH₃)2CH₂P(C(CH₃)3)2)2)(N₂)

: 7440-18-8
ruthenium

Guidance literature:: With Mg; HCl; In tetrahydrofuran-d8; diluted HCl slowly added to Mg in THF-d8 with stirring; 5 min; filtered;Mg washed with dry THF-d8; dried in vac.; mixed with Ru complex and THF -d8; degassed (freeze-pump-thaw cycles using liq. N2); N2 (1 atm) added;stirred (22°C, 1 d); volatiles removed under vac.; C6D6 added; filtered; detd. by (1)H and (31)P NMR spectra;
DOI:10.1039/c0dt00989j