Technology Process of C32H48O5SSi
There total 4 articles about C32H48O5SSi which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 92 percent / H2 / RhCl(PPh3)3 / benzene / 760 Torr
2: DIBAH / toluene / -78 °C
3: PCC / CH2Cl2
4: 1.) LDA, TMSCl / 1.) THF, 2.) CH2Cl2
With
chloro-trimethyl-silane; hydrogen; diisobutylaluminium hydride; pyridinium chlorochromate; lithium diisopropyl amide;
RhCl(PPh3)3;
In
dichloromethane; toluene; benzene;
DOI:10.1021/ja00206a050
- Guidance literature:
-
Multi-step reaction with 2 steps
1: PCC / CH2Cl2
2: 1.) LDA, TMSCl / 1.) THF, 2.) CH2Cl2
With
chloro-trimethyl-silane; pyridinium chlorochromate; lithium diisopropyl amide;
In
dichloromethane;
DOI:10.1021/ja00206a050
- Guidance literature:
-
Multi-step reaction with 3 steps
1: DIBAH / toluene / -78 °C
2: PCC / CH2Cl2
3: 1.) LDA, TMSCl / 1.) THF, 2.) CH2Cl2
With
chloro-trimethyl-silane; diisobutylaluminium hydride; pyridinium chlorochromate; lithium diisopropyl amide;
In
dichloromethane; toluene;
DOI:10.1021/ja00206a050