bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid

Base Information

• Chemical Name: bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid
• CAS No.: 1374643-16-9
• Molecular Formula: CF₃O₃S*C₁₄H₁₄I
• Molecular Weight: 458.24
• Mol file: 1374643-16-9.mol

Synonyms:bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid

Chemical Property of bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid

Chemical Property:

Purity/Quality:

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Technology Process of bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid

There total 3 articles about bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

ortho-methylphenyl iodide (615-37-2) + trifluorormethanesulfonic acid (1493-13-6) + 2-Methylphenylboronic acid (16419-60-6) → bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid (1374643-16-9)

Guidance literature:

ortho-methylphenyl iodide; With boron trifluoride diethyl etherate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃; for 1h; Inert atmosphere;

2-Methylphenylboronic acid; In dichloromethane; at 0 - 20 ℃; for 0.5h; Inert atmosphere;

trifluorormethanesulfonic acid; In dichloromethane; at 20 ℃; for 0.25h; Inert atmosphere;

DOI:10.1002/chem.201102770

Reference yield:

trifluorormethanesulfonic acid (1493-13-6) + 2-(diacetoxyiodo)toluene (31599-59-4) + 2-Methylphenylboronic acid (16419-60-6) → bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid (1374643-16-9)

Guidance literature:

2-Methylphenylboronic acid; With boron trifluoride diethyl etherate; In dichloromethane; at 0 ℃; for 0.166667h;

2-(diacetoxyiodo)toluene; In dichloromethane; at 0 - 20 ℃; for 1.16667h;

trifluorormethanesulfonic acid; In dichloromethane; at 0 - 20 ℃; for 0.333333h;

DOI:10.1039/c7gc02844j

Reference yield:

ortho-methylphenyl iodide (615-37-2) + trifluorormethanesulfonic acid (1493-13-6) + toluene (108-88-3,15644-74-3,16713-13-6) → bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid (1374643-16-9)

Guidance literature:

With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at 20 ℃;

DOI:10.1021/jo501467v

upstream raw materials:

ortho-methylphenyl iodide

trifluorormethanesulfonic acid

2-Methylphenylboronic acid

toluene

Downstream raw materials:

bis(2-methylphenyl)iodonium hexafluorophosphate

2-(2-methylphenyl)-1,4-benzoquinone

2-(2-methylphenyl)-1,4-naphthoquinone