2-(2-Methylphenyl)-p-benzoquinone97%

Base Information

• Chemical Name: 2-(2-Methylphenyl)-p-benzoquinone97%
• CAS No.: 106593-44-6
• Molecular Formula: C₁₃H₁₀O₂
• Molecular Weight: 198.221
• Hs Code.: 2914399090
• Mol file: 106593-44-6.mol

Synonyms:p-Benzoquinone,o-tolyl- (6CI)

Chemical Property of 2-(2-Methylphenyl)-p-benzoquinone97%

Chemical Property:

• PSA: 34.14000
• LogP: 2.08640

Purity/Quality:

2-(2-METHYLPHENYL)-P-BENZOQUINONE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-(2-Methylphenyl)-p-benzoquinone97%

There total 4 articles about 2-(2-Methylphenyl)-p-benzoquinone97% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.7%

2-Methylphenylboronic acid (16419-60-6) + p-benzoquinone (106-51-4) → 2-(2-methylphenyl)-1,4-benzoquinone (106593-44-6)

Guidance literature:

With iron sulfide; dipotassium peroxodisulfate; In dichloromethane; water; at 20 ℃; for 24h;

DOI:10.1039/c2cc35468c

Reference yield: 65.0%

bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid (1374643-16-9) + p-benzoquinone (106-51-4) → 2-(2-methylphenyl)-1,4-benzoquinone (106593-44-6)

Guidance literature:

With sodium hydroxide; In 1,2-dichloro-ethane; for 12h; Reflux;

DOI:10.1021/jo501467v

Reference yield:

toluene (108-88-3,15644-74-3,16713-13-6) → 2-(2-methylphenyl)-1,4-benzoquinone (106593-44-6)

Guidance literature:

Multi-step reaction with 2 steps

1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 20 °C

2: sodium hydroxide / 1,2-dichloro-ethane / 12 h / Reflux

With 3-chloro-benzenecarboperoxoic acid; sodium hydroxide; In dichloromethane; 1,2-dichloro-ethane;

DOI:10.1021/jo501467v

upstream raw materials:

2-methylbenzene diazonium

p-benzoquinone

2-Methylphenylboronic acid

bis(2-methylphenyl)iodonium trifluoromethanesulfonic acid