Trifluoro-methanesulfonic acid 3-benzyloxy-6-[(2S,3R,4S,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl]-2-iodo-phenyl ester

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Chemical Name:Trifluoro-methanesulfonic acid 3-benzyloxy-6-[(2S,3R,4S,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl]-2-iodo-phenyl ester
CAS No.:140201-77-0
Molecular Formula:C₄₁H₃₈F₃IO₈S
Molecular Weight:874.714
Hs Code.:

Synonyms:Trifluoro-methanesulfonic acid 3-benzyloxy-6-[(2S,3R,4S,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl]-2-iodo-phenyl ester

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Chemical Property of Trifluoro-methanesulfonic acid 3-benzyloxy-6-[(2S,3R,4S,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl]-2-iodo-phenyl ester

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Technology Process of Trifluoro-methanesulfonic acid 3-benzyloxy-6-[(2S,3R,4S,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl]-2-iodo-phenyl ester

There total 3 articles about Trifluoro-methanesulfonic acid 3-benzyloxy-6-[(2S,3R,4S,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl]-2-iodo-phenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: 140201-76-9,140201-82-7
3-Benzyloxy-6-[(3R,4S,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl]-2-iodo-phenol

: 140201-77-0
Trifluoro-methanesulfonic acid 3-benzyloxy-6-[(2S,3R,4S,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl]-2-iodo-phenyl ester

Guidance literature:: With i-PrNEt; In dichloromethane; at -78 ℃; for 0.5h;
DOI:10.1021/ja00035a069

Reference yield:

: 140201-75-8
3-(benzyloxy)-2-iodophenol

: 140201-77-0
Trifluoro-methanesulfonic acid 3-benzyloxy-6-[(2S,3R,4S,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl]-2-iodo-phenyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / Cp₂HfCl₂, AgClO₄, 4A molecular sieves / CH₂Cl₂ / -78 - -20 °C

2: 99 percent / i-PrNEt / CH₂Cl₂ / 0.5 h / -78 °C

With bis(cyclopentadienyl)hafnium dichloride; 4 A molecular sieve; i-PrNEt; silver perchlorate; In dichloromethane;
DOI:10.1021/ja00035a069

Reference yield:

: 102935-38-6,140201-74-7,140201-88-3
Acetic acid (3S,4R,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl ester

: 140201-77-0
Trifluoro-methanesulfonic acid 3-benzyloxy-6-[(2S,3R,4S,5R)-3,4-bis-benzyloxy-5-((S)-1-benzyloxy-ethyl)-tetrahydro-furan-2-yl]-2-iodo-phenyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 87 percent / Cp₂HfCl₂, AgClO₄, 4A molecular sieves / CH₂Cl₂ / -78 - -20 °C

2: 99 percent / i-PrNEt / CH₂Cl₂ / 0.5 h / -78 °C

With bis(cyclopentadienyl)hafnium dichloride; 4 A molecular sieve; i-PrNEt; silver perchlorate; In dichloromethane;
DOI:10.1021/ja00035a069