Ph₃SnRe(CO)3(1,10-phenanthroline)

Base Information

• Chemical Name: Ph₃SnRe(CO)3(1,10-phenanthroline)
• CAS No.: 70272-50-3
• Molecular Formula: C₃₃H₂₃N₂O₃ReSn
• Molecular Weight: 800.474
• Mol file: 70272-50-3.mol

Synonyms:Ph₃SnRe(CO)3(1,10-phenanthroline)

Chemical Property of Ph₃SnRe(CO)3(1,10-phenanthroline)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ph₃SnRe(CO)3(1,10-phenanthroline)

There total 1 articles about Ph₃SnRe(CO)3(1,10-phenanthroline) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[Re(CO)3Br(1,10-phenanthroline)] (56812-06-7,62015-31-0) + triphenyltin chloride (639-58-7) → Ph3SnRe(CO)3(1,10-phenanthroline) (70272-50-3)

Guidance literature:

With sodium amalgam; In tetrahydrofuran; Ar, Na/Hg added to a suspension of Re-compound, stirred for 2 h, excessNa/Hg removed, Ph3SnCl in THF added dropwise under protection of light,stirred for 2 h; solvent removed in vacuo, workup in the dark, triturated with C6H6 or CH3C&H5, chromd. (silica gel or alumina), filtrate evapd. to dryness, redissolved (THF), chromd. (silica gel), isooctane added, solvent evapd. slowly; elem. anal.;

DOI:10.1021/ja00547a012

Reference yield:

Ph3SnRe(CO)3(1,10-phenanthroline) (70272-50-3) → Re(CO)3(1,10-phenanthroline) (113110-73-9) + hexaphenylditin (1064-10-4)

Guidance literature:

In not given; Irradiation (UV/VIS); irradiation of soln. of complex (Oriel mercury arc source equipped with an Osram HBO 200-W mercury lamp;

Reference yield:

Ph3SnRe(CO)3(1,10-phenanthroline) (70272-50-3) + t-butylnitrite (917-95-3) → (t-Bu)N(O)Re(CO)3(1,10-phenanthroline) (113132-25-5) + hexaphenylditin (1064-10-4)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); irradn. at room temp. of soln. of complex with t-BuNO as spin trapping reagent (mercury lamp); ESR spect.;

upstream raw materials:

[Re(CO)3Br(1,10-phenanthroline)]

triphenyltin chloride

Downstream raw materials:

(t-Bu)N(O)Re(CO)3(1,10-phenanthroline)

hexaphenylditin

Re(CO)3(1,10-phenanthroline)