Au(1-phenyl-2,3,4,5-tetramethylphosphole)NTf₂

Base Information

• Chemical Name: Au(1-phenyl-2,3,4,5-tetramethylphosphole)NTf₂
• CAS No.: 1425266-23-4
• Molecular Formula: C₁₆H₁₇AuF₆NO₄PS₂
• Molecular Weight: 693.378
• Mol file: 1425266-23-4.mol

Synonyms:Au(1-phenyl-2,3,4,5-tetramethylphosphole)NTf₂

Chemical Property of Au(1-phenyl-2,3,4,5-tetramethylphosphole)NTf₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of Au(1-phenyl-2,3,4,5-tetramethylphosphole)NTf₂

There total 2 articles about Au(1-phenyl-2,3,4,5-tetramethylphosphole)NTf₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I) (1425266-16-5) + silver(I) triflimide (189114-61-2) → Au(1-phenyl-2,3,4,5-tetramethylphosphole)NTf2 (1425266-23-4)

Guidance literature:

In dichloromethane; at 25 ℃; for 0.333333h; Inert atmosphere; Schlenk technique;

DOI:10.1021/om301244m

Reference yield:

2,3,4,5-tetramethyl-1-phenylphosphole (112549-07-2) → Au(1-phenyl-2,3,4,5-tetramethylphosphole)NTf2 (1425266-23-4)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane / 3 h / 22 °C / Inert atmosphere; Schlenk technique

2: dichloromethane / 0.33 h / 25 °C / Inert atmosphere; Schlenk technique

In dichloromethane;

DOI:10.1021/om301244m

upstream raw materials:

chloro-1-phenyl-2,3,4,5-tetramethylphosphole gold(I)

silver(I) triflimide

2,3,4,5-tetramethyl-1-phenylphosphole