(3aS,4S,6S,7aR)-2-(4-methoxybenzyl)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

Base Information

Chemical Name:(3aS,4S,6S,7aR)-2-(4-methoxybenzyl)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole
CAS No.:243145-80-4
Molecular Formula:C₁₈H₂₅BO₃
Molecular Weight:300.206
Hs Code.:

Synonyms:(3aS,4S,6S,7aR)-2-(4-methoxybenzyl)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

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Chemical Property of (3aS,4S,6S,7aR)-2-(4-methoxybenzyl)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

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Technology Process of (3aS,4S,6S,7aR)-2-(4-methoxybenzyl)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

There total 4 articles about (3aS,4S,6S,7aR)-2-(4-methoxybenzyl)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 18680-27-8
pinanediol

: 475250-52-3
2-[(4-methoxyphenyl)methyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 243145-80-4
(3aS,4S,6S,7aR)-2-(4-methoxybenzyl)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

Guidance literature:: In diethyl ether; at 20 ℃;

Reference yield: 63.0%

: 18680-27-8
pinanediol

: 4-methoxybenzylboronic acid

: 243145-80-4
(3aS,4S,6S,7aR)-2-(4-methoxybenzyl)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

Guidance literature:: In diethyl ether; at 20 ℃; for 2h;
DOI:10.1016/j.bmcl.2009.02.117

Reference yield:

: 2746-25-0
p-Methoxybenzyl bromide

: 243145-80-4
(3aS,4S,6S,7aR)-2-(4-methoxybenzyl)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborole

Guidance literature:: Multi-step reaction with 2 steps

1: potassium acetate; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride / 1,4-dioxane / 12 h / 100 °C

2: diethyl ether / 20 °C

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; diethyl ether;