b-bromo-c(N),d(N')-{N,N-diethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(1-)}-a-pyridineplatinum(II)

Base Information

• Chemical Name: b-bromo-c(N),d(N')-{N,N-diethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(1-)}-a-pyridineplatinum(II)
• CAS No.: 138612-86-9
• Molecular Formula: C₁₇H₂₀BrF₄N₃Pt
• Molecular Weight: 617.344

Synonyms:b-bromo-c(N),d(N')-{N,N-diethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(1-)}-a-pyridineplatinum(II)

Chemical Property of b-bromo-c(N),d(N')-{N,N-diethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(1-)}-a-pyridineplatinum(II)

Chemical Property:

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Technology Process of b-bromo-c(N),d(N')-{N,N-diethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(1-)}-a-pyridineplatinum(II)

There total 2 articles about b-bromo-c(N),d(N')-{N,N-diethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato^(1-)}-a-pyridineplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

thallium(I) pentafluorobenzoate (68558-86-1) + dibromo(N,N-diethylethane-1,2-diamine)platinum(II) (138772-32-4) + Pentafluorobenzene (363-72-4) → b-bromo-c(N),d(N')-{N,N-diethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato(1-)}-a-pyridineplatinum(II) (138612-86-9)

Guidance literature:

With C₅H₅N; In pyridine; byproducts: CO2, TlBr; placing Pt-complex and Tl-salt in a Schlenk flask (condenser, Ba(OH)2 trap; purging with N2); addn. of pyridine and C6F5H by syringe under N2; heating at 100°C for 1h with stirring (CO2 evolved); cooling; removing solvent under vac.; stirring dark residue with petroleum overnight; extn. (ether); filtration of ether extract; concg. by evapn.; addn. of light petroleum; evapg. until crystn. occurs; careful recrystn. (ether/light petroleum); elem. anal.;

Reference yield:

N,N-diethylethylenediamine (100-36-7) → b-bromo-c(N),d(N')-{N,N-diethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato(1-)}-a-pyridineplatinum(II) (138612-86-9)

Guidance literature:

Multi-step reaction with 3 steps

1: KI / water

2: AgNO₃; KBr / water

3: C₅H₅N / pyridine

With KI; AgNO₃; KBr; C₅H₅N; In pyridine; water;

Reference yield:

b-bromo-c(N),d(N')-{N,N-diethyl-N'-(2,3,5,6-tetrafluorophenyl)ethane-1,2-diaminato(1-)}-a-pyridineplatinum(II) (138612-86-9) → trans-[Pt{(p-HC6F4)NCH=C(Br)NEt2}Br(pyridine)]

Guidance literature:

With dihydrogen peroxide; In acetonitrile; at 60 ℃; for 22h;

DOI:10.1016/j.jinorgbio.2021.111360

upstream raw materials:

thallium(I) pentafluorobenzoate

dibromo(N,N-diethylethane-1,2-diamine)platinum(II)

Pentafluorobenzene

N,N-diethylethylenediamine

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